(triphenylphosphine)(tetraphenyldiselenoimidodiphosphinato)copper(I) | 237427-33-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: (triphenylphosphine)(tetraphenyldiselenoimidodiphosphinato)copper(I)
• CAS: 237427-33-7
• 化学式: C₄₂H₃₅CuNP₃Se₂
• 分子量: 868.134
• InChiKey: XEMAEZBEHNOFHL-UHFFFAOYSA-N

反应信息

• 作为产物：
  描述：

  bis(triphenylphosphane)copper(I) nitrate 、 potassium bis(diphenylselenophosphoryl)amide 以 甲醇 、 氯仿 为溶剂， 以86%的产率得到(triphenylphosphine)(tetraphenyldiselenoimidodiphosphinato)copper(I)
  参考文献：
  名称：

  Displacement of triphenylphosphine from Cu(PPh3)2NO3 and Co(PPh3)2Cl2 by a diselenoimidodiphosphinato ligand. X-ray crystal structure of (PPh3)Cu[Ph2P(Se)NP(Se)Ph2] and Co[Ph2P(Se)NP(Se)Ph2]2 containing the novel CuSe2P2N and CoSe2P2N inorganic metallocycles

  摘要：

  The reaction of Cu(PPh3)(2)NO3 with K[Ph2P(Se)-N-P(Se)Ph-2] produced a tricoordinate copper(I) complex, Cu(PPh3)[Ph2P(Se)-N-P(Se)Ph-2], containing the novel inorganic (carbon-free) CuSe2P2N metallocycle. The same diselenium reagent: gave with Co(PPh3)(2)Cl-2 a spirobicyclic compound Co[Ph2P(Se)-N-P(Se)Ph-2](2), containing the novel inorganic CoSe2P2N metallocycle. The crystal structure of the two compounds was investigated by X-ray diffraction. In both compounds the inorganic metallocycles are nonplanar and display strongly distorted twisted boat conformations. (C) 1999 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0020-1693(99)00154-1