1-Heptadecafluorooctyl-4-methyl-benzene | 82396-51-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1-Heptadecafluorooctyl-4-methyl-benzene
• 英文别名: 1-(Heptadecafluorooctyl)-4-methylbenzene；1-(1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-heptadecafluorooctyl)-4-methylbenzene
• CAS: 82396-51-8
• 化学式: C₁₅H₇F₁₇
• 分子量: 510.193
• InChiKey: MTNQRVPPULDKMX-UHFFFAOYSA-N

物化性质

• 沸点：
  244.7±40.0 °C(Predicted)
• 密度：
  1.539±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  7.9
• 重原子数：
  32
• 可旋转键数：
  7
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.6
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  17

反应信息

• 作为产物：
  描述：

  [1,1,2,2,3,3,4,4,5,5,6,6,7,7,8,8,8-Heptadecafluorooctyl(phenyl)-lambda3-iodanyl] 2,2,2-trifluoroacetate 、 对甲苯基氯化镁 、 四氢呋喃 以8%的产率得到
  参考文献：
  名称：

  UMEMOTO, TERUO;GOTOH, YOSHIHIKO, BULL. CHEM. SOC. JAP., 1986, 59, N 2, 439-445

  摘要：

  DOI：

文献信息

• Perfluorooctylation of aromatic compounds with perfluoroazooctane upon 185 nm irradiation in a two-phase system
  作者：Takako Nakamura、Yoshinori Koga

  DOI：10.1039/a707171j

  日期：——

  An efficient method for the preparation of perfluorooctylated aromatic and heteroaromatic compounds has been developed using photolysis of perfluoroazooctane (E)-1 upon 185 nm irradiation. The use of a two-phase system made up of a perfluorohexane solution of (E)-1 and a suitable aromatic compound has proved efficient for this reaction. The photolytic mechanism of (E)-1 upon 185 nm irradiation has also been investigated on the basis of quantum yield, light intensity dependence and UV–VIS spectra. It is shown that (E)-1 is photoisomerized by one photon absorption to the (Z)-isomer, with subsequent extrusion of nitrogen by a second photon absorption.

  利用全氟辛烷 (E)-1 在 185 纳米波长照射下的光解作用，开发出了一种制备全氟辛基芳香族和杂芳香族化合物的有效方法。事实证明，使用由(E)-1 的全氟己烷溶液和适当的芳香族化合物组成的两相体系可以有效地进行该反应。根据量子产率、光强依赖性和紫外-可见光谱，还研究了 (E)-1 在 185 纳米辐照下的光解机理。研究表明，(E)-1 通过一次光子吸收发生光异构化，生成 (Z)- 异构体，随后通过第二次光子吸收挤出氮。
• JPS5718638A
  申请人：——

  公开号：JPS5718638A

  公开（公告）日：1982-01-30
• FLUORINE-BRIDGED ASSOCIATIONS FOR OPTOELECTRONIC APPLICATIONS
  申请人：Buchholz Herwig

  公开号：US20110095283A1

  公开（公告）日：2011-04-28

  The present invention relates to a fluorine-bridged associate consisting of an oligomer or polymer containing fluorine radicals which are bonded to the oligomer or polymer backbone, and up to three types of functional units in the backbone which differ with respect to function and are selected from the group consisting of a hole-transport and/or hole-injection unit, an electron-transport and/or electron-injection unit and an emitter unit, and one to three types of compounds containing a fluorine radical which differ with respect to function and are selected from a hole-transport and/or hole-injection unit, an electron-transport and/or electron-injection unit and an emitter unit, and to an opto-electronic device in which the fluorine-bridged associate is employed.
• US9080099B2
  申请人：——

  公开号：US9080099B2

  公开（公告）日：2015-07-14