di-μ-acetato-bis[[2,4-dichloro-6-(2-pyridylmethyliminomethyl)phenolato]zinc(II)] | 881035-51-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: di-μ-acetato-bis[[2,4-dichloro-6-(2-pyridylmethyliminomethyl)phenolato]zinc(II)]
• CAS: 881035-51-4
• 化学式: C₃₀H₂₄Cl₄N₄O₆Zn₂
• 分子量: 809.136
• InChiKey: PRPLZWAJOYKHTD-FVTUAKQPSA-J

反应信息

• 作为产物：
  描述：

  zinc(II) acetate dihydrate 、 2-氨甲基吡啶 、 3,5-二氯水杨醛 以 甲醇 为溶剂， 生成 di-μ-acetato-bis[[2,4-dichloro-6-(2-pyridylmethyliminomethyl)phenolato]zinc(II)]
  参考文献：
  名称：

  Di-μ-acetato-bis{[2,4-dichloro-6-(2-pyridylmethyliminomethyl)phenolato]zinc(II)} and di-μ-thiocyanato-bis{[2,4-dichloro-6-(2-pyridylmethyliminomethyl)phenolato]copper(II)}

  摘要：

  The two title complexes, [Zn(2)(C(13)H(9)Cl(2)N(2)O)(2)(C(2)H(3)O(2))(2)], (I), and [Cu(2)(C(13)H(9)Cl(2)N(2)O)(2)(NCS)(2)], (II), are dinuclear Schiff base compounds. Both molecules are located on crystallographic centres of inversion. In (I), the Zn(II) atom is five-coordinated in a trigonal-bipyramidal coordination, with one imine N atom of one Schiff base and two acetate O atoms defining the basal plane, and one O atom and one pyridine N atom of the Schiff base occupying the axial positions, while in (II), the Cu(II) atom is five-coordinated in a square-pyramidal coordination, with one O and two N atoms of one Schiff base and one terminal N atom of a bridging thiocyanate ligand defining the basal plane, and one terminal S atom of another bridging thiocyanate ligand occupying the apical position. The different bridging ligands lead to the different coordinations of the complexes.

  DOI：

  10.1107/s0108270105030192