di(thiocyanato-N)(2,4-diphenyl-1,5-diaza-8,11-dioxo-6,7:12,13-dibenzocyclotrideca-1,4-diene[N2O2]ane)cobalt(II) | 864415-94-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 苯并三唑类
• 英文名称: di(thiocyanato-N)(2,4-diphenyl-1,5-diaza-8,11-dioxo-6,7:12,13-dibenzocyclotrideca-1,4-diene[N2O2]ane)cobalt(II)
• CAS: 864415-94-1
• 化学式: C₃₁H₂₄CoN₄O₂S₂
• 分子量: 607.682
• InChiKey: RGBIBSJYICYOQK-LNENZVTOSA-N

反应信息

• 作为产物：
  描述：

  cobalt(II) thiocyanate hydrate 、 2,4-diphenyl-1,5-diaza-8,11-dioxo-6,7:12,13-dibenzocyclotrideca-1,4-diene[N2O2]ane 以 乙醇 为溶剂， 以50%的产率得到di(thiocyanato-N)(2,4-diphenyl-1,5-diaza-8,11-dioxo-6,7:12,13-dibenzocyclotrideca-1,4-diene[N2O2]ane)cobalt(II)
  参考文献：
  名称：

  钴 (II) 和锰 (II) 配合物与 12-、14-、15- 和 18 元 N4、N2O2、N2O2S、N6 供体大环配体的合成、电化学和光谱研究

  摘要：

  13-, 14-, 15-, and 18-membered N2O2, N-4, N2O2S, and N-6 donor macrocyclic ligands and their complexes with cobalt(II) and manganese( II) of the general composition ML,(NCS)(2) (where M 5 cobalt( II) and manganese( II) and ligands L 5 L 1, L 2, L 3, and L 4 have been synthesized. All of the macrocyclic ligands and their complexes have been characterized by elemental analyses, IR, mass, H-1 NMR, magnetic moments, electronic and EPR spectral studies. The structures of the complexes and the various coordinating groups such as > C=N, > CONH, Ph-O-CH2- and > NH are discussed. The redox properties of the complexes were examined by cyclic voltammetery. They exhibit a high potential Co(III)/Co(II) couple along with ligand reduction.

  DOI：

  10.1081/sim-200035709