| 1448179-89-2

• 分子结构分类: 有机化合物 - 苯类化合物
• CAS: 1448179-89-2
• 化学式: C₁₆H₁₄Cl₄CoN₂O₆
• 分子量: 531.102
• InChiKey: KGIQSWRNEUXVLO-CRDWRNGRSA-L

反应信息

• 作为产物：
  描述：

  4,4',6,6'-tetrachloro-2,2'-[ethylenedioxybis(nitrilomethylidene)]diphenol 、 cobalt(II) diacetate tetrahydrate 以 甲醇 、 乙酸乙酯 、 丙酮 为溶剂， 以43.8%的产率得到
  参考文献：
  名称：

  Synthesis, Characterization, and Crystal Structure of a Supramolecular Co^II Complex Containing Salen-Type Bisoxime

  摘要：

  A supramolecular CoII complex, [CoL(H2O)2], bearing Salen-type bisoxime chelate ligand 4,4,6,6-tetrachloro-2,2-[ethylenedioxybis(nitrilomethylidyne)]diphenol (H2L), has been synthesized and structurally characterized by elemental analyses, IR spectra, UVvis spectra, and X-ray diffraction techniques. The crystal structure of [CoL(H2O)2] indicates that the CoII complex consists of one CoII atom, one L2 unit, and two coordinated water molecules. The CoII complex exhibits slightly distorted octahedral geometry with the Salen-type bisoxime ligand forming the basal N2O2 coordination plane and two oxygen atoms from the coordinated water molecules in the axial positions. An infinite 1D metalwater chain and 2D supramolecular network structure were formed by intermolecular O-H center dot center dot center dot O, O-H center dot center dot center dot Cl, and C-H center dot center dot center dot O hydrogen bonding and - stacking interactions. Supplemental materials are available for this article. Go to the publisher's online edition of Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry to view the supplemental file.

  DOI：

  10.1080/15533174.2012.751424