(4aR,6R,7S,7aR)-6-(6-Amino-purin-9-yl)-2-oxo-hexahydro-2λ⁵-cyclopenta[1,3,2]dioxaphosphinine-2,7-diol; compound with triethyl-amine | 96292-24-9

• 分子结构分类: 有机化合物 - 核苷、核苷酸和类似物
• 英文名称: (4aR,6R,7S,7aR)-6-(6-Amino-purin-9-yl)-2-oxo-hexahydro-2λ⁵-cyclopenta[1,3,2]dioxaphosphinine-2,7-diol; compound with triethyl-amine
• CAS: 96292-24-9
• 化学式: C₆H₁₅N*C₁₁H₁₄N₅O₅P
• 分子量: 428.428
• InChiKey: DEMONIVFVQQSTP-QPOALRDDSA-N

反应信息

• 作为产物：
  描述：

  aristeromycin 5'-phosphorimidazolide 在 magnesium 作用下， 反应 120.0h， 以1.8%的产率得到(4aR,6R,7S,7aR)-6-(6-Amino-purin-9-yl)-2-oxo-hexahydro-2λ⁵-cyclopenta[1,3,2]dioxaphosphinine-2,7-diol; compound with triethyl-amine
  参考文献：
  名称：

  Preparation of cyclic AMP derivatives by intramolecular phosphodiester bond formation catalyzed by Pb2+ ion.

  摘要：

  Cyclic AMP derivatives containing a carbocyclic sugar moiety were prepared by lead-ion catalyzed intramolecular phosphodiester-bond formation of carbocyclic nucleoside-5'-phosphorimidazolide in aqueous solution. The catalytic effect of other metal ions and the properties of the cyclic AMP derivatives are described.

  DOI：

  10.1248/cpb.33.432