1-[[4-[[3,5-Bis[[4-[(2-hydroxynaphthalen-1-yl)methylideneamino]phenoxy]methyl]-2,4,6-trimethylphenyl]methoxy]phenyl]iminomethyl]naphthalen-2-ol | 1419639-47-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 萘
• 英文名称: 1-[[4-[[3,5-Bis[[4-[(2-hydroxynaphthalen-1-yl)methylideneamino]phenoxy]methyl]-2,4,6-trimethylphenyl]methoxy]phenyl]iminomethyl]naphthalen-2-ol
• CAS: 1419639-47-6
• 化学式: C₆₃H₅₁N₃O₆
• 分子量: 946.114
• InChiKey: MWDCTNJXPPDHTA-UHFFFAOYSA-N

物化性质

• 密度：
  1.21±0.1 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  14
• 重原子数：
  72
• 可旋转键数：
  15
• 环数：
  10.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  126
• 氢给体数：
  3
• 氢受体数：
  9

反应信息

• 作为产物：
  描述：

  在 palladium 10% on activated carbon 、 一水合肼 作用下， 以 甲醇 为溶剂， 反应 12.0h， 生成 1-[[4-[[3,5-Bis[[4-[(2-hydroxynaphthalen-1-yl)methylideneamino]phenoxy]methyl]-2,4,6-trimethylphenyl]methoxy]phenyl]iminomethyl]naphthalen-2-ol
  参考文献：
  名称：

  Selective fluorescence sensor for Al3+ and Pb2+ in physiological condition by a benzene based tripodal receptor

  摘要：

  We have synthesized a benzene based tripodal receptor containing naphthalene motifs as signaling unit. The receptor can selectively bind Al3+/Pb2+ metal ions with a significant change in its fluorescence and UV/Vis spectra, while the addition of other metal ions (Na+, K+, Ca2+, Mg2+, Cr3+, Hg-2, Cu2+, Zn2+, Fe2+, Co2+, Ni2+, Cd2+, and Ag+) produces insignificant or minor changes. The formation of receptor-metal ion complex is also proved by NMR and mass spectroscopic analysis. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tetlet.2012.11.114

文献信息

• Fluorescent naphthalene-based benzene tripod for selective recognition of fluoride in physiological condition
  作者：BARUN KUMAR DATTA、CHIRANTAN KAR、GOPAL DAS

  DOI：10.1007/s12039-015-0779-0

  日期：2015.2

  Aluminium complex of a naphthalene-based benzene tripod ligand system has been reported for the selective recognition of fluoride in aqueous medium in physiological condition. The ligand can selectively recognize Al3+ through enhancement in the fluorescence intensity and this in situ formed aluminium complex recognizes fluoride through quenching of fluorescence. The receptor system detects fluoride

  据报道，基于萘的苯三脚架配体系统的铝络合物可在生理条件下选择性识别水性介质中的氟化物。配体可以通过增强荧光强度来选择性地识别Al 3+，并且这种原位形成的铝络合物通过猝灭荧光来识别氟化物。受体系统检测纳摩尔范围内的氟化物。传感特性得到扩展，可用于自来水，池塘水和河水中的氟化物传感。 高荧光的三脚架铝络合物用于感测生理条件和废水中的氟化物。