4-(4-甲氧基苯甲酰基)苯基乙酸酯 | 97576-09-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 中文名称: 4-(4-甲氧基苯甲酰基)苯基乙酸酯
• 英文名称: 4-Acetoxy-4'-methoxybenzophenon
• 英文别名: 4-Acetoxy-4'-methoxybenzophenone；[4-(4-methoxybenzoyl)phenyl] acetate
• CAS: 97576-09-5
• 化学式: C₁₆H₁₄O₄
• 分子量: 270.285
• InChiKey: VELFRRABQLNHOP-UHFFFAOYSA-N

物化性质

• 熔点：
  110 °C
• 沸点：
  420.0±30.0 °C(Predicted)
• 密度：
  1.179±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.9
• 重原子数：
  20
• 可旋转键数：
  5
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.12
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 海关编码：
  2915390090

反应信息

• 作为产物：
  描述：

  4-acetoxybenzoyl chloride 、 iodomanganese(1+),methoxybenzene 以 乙醚 为溶剂， 反应 2.0h， 以82%的产率得到4-(4-甲氧基苯甲酰基)苯基乙酸酯
  参考文献：
  名称：

  Organomanganese(II) Reagents; X¹. A Convenient Preparation of Various Acetoxyketones, Keto-nitriles, Keto-esters, Keto-acids, Diketones, and Heterocyclic Ketones (Acylheterocycles) via Acylation of Organomanganese(II) Reagents

  摘要：

  DOI：

  10.1055/s-1985-31101

文献信息

• FRIOUR, G.;CAHIEZ, G.;NORMANT, J. F., SYNTHESIS, BRD, 1985, N 1, 50-54
  作者：FRIOUR, G.、CAHIEZ, G.、NORMANT, J. F.

  DOI：——

  日期：——
• Sulfur-Containing Compound, Method for Producing Same, Sulfur-Containing Polymer, and Optical Material
  申请人：Takashima Yoriyuki

  公开号：US20080146759A1

  公开（公告）日：2008-06-19

  The present invention provides a polythiocarbonate resin containing a repeating unit represented by the following general formula (1), having high transparency, refractive index, and Abbe number and excellent heat resistance and impact resistance, and an optical material using the polythiocarbonate resin. Further, the present invention provides a sulfur-containing compound having an Abbe number of 40 or more, a high refractive index, a high Abbe number, excellent transparency, excellent heat resistance, and the like, obtained by reacting a dithiol compound represented by the following general formula (II) and a diene compound represented by the following general formula (III), and thus containing a repeating unit formed of a structural unit derived from a residue of the dithiol compound and a structural unit derived from a residue of the diene compound. Still further, the present invention provides a method of producing the sulfur-containing compound, a sulfur-containing polymer including the sulfur-containing compound as a constitutional component, and an optical material containing the sulfur-containing polymer. HS-G 1 -SH   (II) G 2″ (III)
• Organomanganese(II) Reagents; X¹. A Convenient Preparation of Various Acetoxyketones, Keto-nitriles, Keto-esters, Keto-acids, Diketones, and Heterocyclic Ketones (Acylheterocycles) via Acylation of Organomanganese(II) Reagents
  作者：G. Friour、G. Cahiez、J. F. Normant

  DOI：10.1055/s-1985-31101

  日期：——