2,9,26,23-tetra-(3-pyridyloxy)phthalocyanine zinc(II) | 93365-80-1

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 四吡咯及其衍生物
• 英文名称: 2,9,26,23-tetra-(3-pyridyloxy)phthalocyanine zinc(II)
• 英文别名: 2(3),9(10),16(17),23(24)-tetrakis-(pyridin-3-oxyl)phthalocyaninato zinc(II)；zinc;6,15,24,33-tetrapyridin-3-yloxy-2,11,20,29,37,39-hexaza-38,40-diazanidanonacyclo[28.6.1.13,10.112,19.121,28.04,9.013,18.022,27.031,36]tetraconta-1,3,5,7,9,11,13(18),14,16,19(39),20,22(27),23,25,28,30(37),31(36),32,34-nonadecaene
• CAS: 93365-80-1
• 化学式: C₅₂H₂₈N₁₂O₄Zn
• 分子量: 950.262
• InChiKey: BKIDIYMNLRBUSV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  2,9,26,23-tetra-(3-pyridyloxy)phthalocyanine zinc(II) 在 碘甲烷 作用下， 以 N,N-二甲基甲酰胺 为溶剂， 以77%的产率得到zinc tetrakis(3-methylpyridyloxy)phthalocyanide
  参考文献：
  名称：

  在面对面的锰卟啉和锌酞菁异络合物中光诱导的混合价Mn IV -Mn II，Mn IV -Mn III，Mn III -Mn II的形成

  摘要：

  混合价Mn的光诱导形成IV P-的ZnPc - -Mn III磷，锰III P-的ZnPc + -Mn II P，和的ZnPc + -Mn II P-的ZnPc - -Mn IV被报导的P络合物。可以通过监测卟啉和酞菁化学计量来控制它们的形成。通过堆叠的面对面杂聚物形成多个电子。中的Mn的奇特稳定性IV P-的ZnPc - -Mn III P物种在锌四（3- methylpyridyloxy）酞菁的氧化还原特有性能方面进行了说明。

  DOI：

  10.1016/0009-2614(88)87281-6
• 作为产物：
  描述：

  4-(3-pyridyloxy)phthalonitrile 以85%的产率得到
  参考文献：
  名称：

  WOHRLE D., ISKANDER N., GRASCHEW G., SINN N., FRIEDRICH E. A., MAIERBORST+, PROTOCHEM. AND PHOTOBIOL. 1990, 51, N3, 351-356

  摘要：

  DOI：

文献信息

• Umbelliferone Decorated Water‐soluble Zinc(II) Phthalocyanines – <i>In Vitro</i> Phototoxic Antimicrobial Anti‐cancer Agents
  作者：Andrea Sowa、Alexander Höing、Ulrich Dobrindt、Shirley K. Knauer、Anzhela Galstyan、Jens Voskuhl

  DOI：10.1002/chem.202102255

  日期：2021.10.21

  Presented here are umbelliferone substituted water-soluble zinc(II) phthalocyanines, which are able to inactivate efficiently Gram-positive and Gram-negative bacteria and are also active against HepG2 cancer cells. The compounds were investigated concerning their phototoxicity as well as their photophysical properties and their aggregation behavior.

  这里介绍的是伞形酮取代的水溶性锌 (II) 酞菁，它能够有效灭活革兰氏阳性和革兰氏阴性细菌，并且对 HepG2 癌细胞也有活性。研究了这些化合物的光毒性、光物理性质和聚集行为。
• Synthesis and photochemical properties of phthalocyanine zinc(II) complexes containing o-carborane units
  作者：Dieter Wöhrle、Olga Tsaryova、Andrey Semioshkin、Detlef Gabel、Olga Suvorova

  DOI：10.1016/j.jorganchem.2013.03.020

  日期：2013.12

  The synthesis and characterization of novel phthalocyanine zinc(II) complexes containing o-carborane units are described. The following properties of o-carboranyl-substituted phthalocyanines were investigated: singlet oxygen quantum yield, photo-oxidative stability, photocatalytic activity in the photooxidation of (S)-(-)-citronellol. The o-carboranyl substituted phthalocyanine zinc(II) complexes exhibit improved singlet oxygen quantum yields, photo-oxidative stabilities, photocatalytic activities compared to phthalocyanine zinc(II) complexes without o-carboranyl groups. Therefore these o-carboranyl complexes are of interest for use in cancer therapy. (C) 2013 Elsevier B. V. All rights reserved.