硫酸四氨合铜水合物 | 14283-05-7

• 物质功能分类: 有机原料 - 羧酸类化合物及衍生物
• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属氧阴离子化合物
• 中文名称: 硫酸四氨合铜水合物
• 中文别名: 四胺硫酸铜水合物；四氨合铜硫酸盐N水
• 英文名称: tetramminecopper(II) sulfate
• 英文别名: Copper(2+), tetraammine-, sulfate (1:1)；copper;azane;sulfate
• CAS: 14283-05-7
• 化学式: CuH₁₂N₄*O₄S
• 分子量: 227.732
• InChiKey: MJIHMGIXWVSFTF-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  -0.69
• 重原子数：
  10
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  92.6
• 氢给体数：
  4
• 氢受体数：
  8

安全信息

• 安全说明：
  S22,S24/25

SDS

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Section 1: Product Identification
Chemical Name: Tetraamminecopper (II) sulfatehydrate
CAS Registry Number: 14283-05-7
Formula: [Cu(NH3)4]SO4.XH2O
EINECS Number: none
Chemical Family: metal-ammine complexes
Synonym: None

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Section 2: Composition and Information on Ingredients
Ingredient CAS Number Percent ACGIH (TWA) OSHA (PEL)
Title Compound 14283-05-7 100% 1mg/m3 (as Cu) 1mg/m3 (as Cu)

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Section 3: Hazards Identification
Emergency Overview: Irritating to skin, eyes and respiratory tract.
Primary Routes of Exposure: Ingestion, inhalation
Eye Contact: Causes slight to mild irritation of the eyes
Skin Contact: Causes slight to mild irritation of the skin.
Inhalation: Irritating to the nose, mucous membranes and respiratory tract.
Ingestion: Ingestion of copper compounds may lead to vomiting, exhaustion, anemia, convulsions and coma.
Acute Health Affects: Irritating to skin, eyes and respiratory tract.
Chronic Health Affects: No information available on long-term chronic effects.
NTP: No
IARC: No
OSHA: No

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SECTION 4: First Aid Measures
Immediately flush the eyes with copious amounts of water for at least 10-15 minutes. A victim may need
Eye Exposure:
assistance in keeping their eye lids open. Get immediate medical attention.
Wash the affected area with water. Remove contaminated clothes if necessary. Seek medical assistance if
Skin Exposure:
irritation persists.
Remove the victim to fresh air. Closely monitor the victim for signs of respiratory problems, such as difficulty
Inhalation:
in breathing, coughing, wheezing, or pain. In such cases seek immediate medical assistance.
Seek medical attention immediately. Keep the victim calm. Give the victim water (only if conscious). Induce
Ingestion:
vomiting only if directed by medical personnel.

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SECTION 5: Fire Fighting Measures
Flash Point: none
Autoignition Temperature: none
Explosion Limits: none
Extinguishing Medium: carbon dioxide, foam or dry powder
If this product is involved in a fire, fire fighters should be equipped with a NIOSH approved positive pressure
Special Fire Fighting Procedures:
self-contained breathing apparatus and full protective clothing.
Hazardous Combustion and If involved in a fire this material may emit irritating fumes.
Decomposion Products:
Unusual Fire or Explosion Hazards: No unusual fire or explosion hazards.

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SECTION 6: Accidental Release Measures
Spill and Leak Procedures: Small spills can be mixed with vermiculite or sodium carbonate and swept up.

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SECTION 7: Handling and Storage
Handling and Storage: Store in a tightly sealed container.

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SECTION 8: Exposure Controls and Personal Protection
Eye Protection: Always wear approved safety glasses when handling a chemical substance in the laboratory.
Skin Protection: Wear protective clothing and gloves.
Ventilation: Material may form a fine dust. If possible, handle the material in an efficient fume hood.
If ventilation is not available a respirator should be worn. The use of respirators requires a Respirator
Respirator:
Protection Program to be in compliance with 29 CFR 1910.134.
Ventilation: Material may form a fine dust. If possible, handle the material in an efficient fume hood.
Additional Protection: No additional protection required.

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SECTION 9: Physical and Chemical Properties
Color and Form: blue xtl.
Molecular Weight: 227.72
Melting Point: no data
Boiling Point: no data
Vapor Pressure: not applicable
Specific Gravity: no data
Odor: None
Solubility in Water: soluble

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SECTION 10: Stability and Reactivity
Stability: air and moisture stable
Hazardous Polymerization: no hazardous polymerization
Conditions to Avoid: contact with strong oxidizing agents
Incompatibility: oxidizing agents, azides and acetylene
Decomposition Products: Ammonia, sulfur dioxide, and copper salts

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SECTION 11: Toxicological Information
RTECS Data: No specific information available on this product.
Carcinogenic Effects: No data available
Mutagenic Effects: No data available
Tetratogenic Effects: No data available

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SECTION 12: Ecological Information
Ecological Information: No information available

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SECTION 13: Disposal Considerations
Disposal: Dispose of according to local, state and federal regulations.

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SECTION 14: Transportation
Shipping Name (CFR): Non-hazardous
Hazard Class (CFR): NA
Additional Hazard Class (CFR): NA
Packaging Group (CFR): NA
UN ID Number (CFR): NA
Shipping Name (IATA): Non-hazardous
Hazard Class (IATA): NA
Additional Hazard Class (IATA): NA
Packaging Group (IATA): NA
UN ID Number (IATA): NA

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SECTION 15: Regulatory Information
TSCA: listed on the TSCA inventory
SARA (Title 313): Title Compound: see Category Code N100 for reporting.
Second Ingredient: none

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SECTION 16 - ADDITIONAL INFORMATION
N/A

反应信息

• 作为反应物：
  描述：

  硫酸四氨合铜水合物 以 水 为溶剂， 生成 copper hydroxide
  参考文献：
  名称：

  Dawson, D. M., Chemische Berichte, 1909, vol. 42, p. 720 - 726

  摘要：

  DOI：
• 作为产物：
  描述：

  copper(II) sulfate*NH3 以 neat (no solvent) 为溶剂， 生成 硫酸四氨合铜水合物
  参考文献：
  名称：

  Peters, W., Zeitschrift fur anorganische Chemie, 1912, vol. 77, p. 137 - 190

  摘要：

  DOI：

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Cu: MVol.B1, 72, page 149 - 154
  作者：

  DOI：——

  日期：——
• Emmert, B.; Brandl, F., Chemische Berichte, 1927, vol. 60, p. 2211 - 2216
  作者：Emmert, B.、Brandl, F.

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Cu: MVol.B4, 115, page 1693 - 1696
  作者：

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Cu: MVol.B1, 260, page 589 - 591
  作者：

  DOI：——

  日期：——
• X.—The metallic derivatives of nitrogen iodide and their bearing on its constitution
  作者：Oswald Silberrad

  DOI：10.1039/ct9058700066

  日期：——