Al2Br4(anisol)2 | 155962-10-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Al2Br4(anisol)2
• CAS: 155962-10-0
• 化学式: C₁₄H₁₆Al₂Br₄O₂
• 分子量: 589.859
• InChiKey: FAQCKLXNIVWFII-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  Al2Br4(anisol)2 以 not given 为溶剂， 生成 氢化铝 、 anisole; compound with aluminium bromide
  参考文献：
  名称：

  Aluminum(I) and Gallium(I) Compounds: Syntheses, Structures, and Reactions

  摘要：

  AbstractBy the end of the last century there were already the first indications of the possible existence of Al1 halides. However, it was only through the pioneering works of W. Klemm, who would have celebrated his 100th birthday on January 6, 1996, that detailed spectroscopic investigations became possible. Since the end of the 1970s the reactivity of AlX and GaX species in solid noble gases has been confirmed by numerous examples. In recent years formally monovalent Al and Ga species have been successfully synthesized on a preparative scale. In addition to the first halides, organometallic compounds with metal–metal bonds have been isolated and investigated with regard to their chemical properties. The fundamental importance of such species has been documented in this journal among others in the form of two highlight articles in which experimental and theoretical aspects have been examined with examples, and parallels and differences with respect to boron chemistry have been illustrated. This review is intended to give an account of the chronological development of this research area over the last few years, but an attempt is also made to categorize the experimental results achieved not only with respect to structure, thermodynamics, and reactivity, but also with the aid of quantum chemical calculations and by comparative considerations.

  DOI：

  10.1002/anie.199601291
• 作为产物：
  描述：

  aluminum (I) bromide 、 三溴化铝 、 苯甲醚 以 正戊烷 为溶剂， 生成 Al2Br4(anisol)2
  参考文献：
  名称：

  Mocker, Mario; Robl, Christian; Schnoeckel, Hansgeorg, Angewandte Chemie, 1994, vol. 106, p. 946 - 948

  摘要：

  DOI：