Methyl-benzyl-phosphin | 90085-45-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: Methyl-benzyl-phosphin
• 英文别名: Benzyl methyl phosphine；benzyl(methyl)phosphane
• CAS: 90085-45-3
• 化学式: C₈H₁₁P
• 分子量: 138.149
• InChiKey: KRSLQQZPMAKZNR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.9
• 重原子数：
  9
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  Methyl-benzyl-phosphin 在 吡啶 作用下， 以 1,2-二氯乙烷 、 Petroleum ether 为溶剂， 生成 Methyl-benzyl-phosphinigsaeure-ethylester
  参考文献：
  名称：

  Steininger,E., Chemische Berichte, 1963, vol. 96, p. 3184 - 3194

  摘要：

  DOI：
• 作为产物：
  描述：

  O-ethyl-benzyl-methylphosphinate 在 lithium aluminium tetrahydride 作用下， 生成 Methyl-benzyl-phosphin
  参考文献：
  名称：

  Steininger,E., Chemische Berichte, 1963, vol. 96, p. 3184 - 3194

  摘要：

  DOI：

文献信息

• POLYMERS WITH TUNABLE BAND GAPS FOR PHOTONIC AND ELECTRONIC APPLICATIONS
  申请人：You Wei

  公开号：US20130092912A1

  公开（公告）日：2013-04-18

  The present invention provides, among other things, a copolymer comprising at least one donor monomer and at least one acceptor monomer. The polymer may optionally further comprise at least one additional comonomer. The polymers are useful as a charge-transport, semiconducting, electrochemical conducting, photoconducting, or light emitting material. Microelectronic devices comprising such polymers (e.g., as a heterojunction therein) are also described.

  本发明提供了一种共聚物，包括至少一个给体单体和至少一个受体单体。该聚合物可以选择性地进一步包括至少一个额外的共聚单体。这些聚合物可用作电荷传输、半导体、电化学导电、光导电或发光材料。还描述了包括这些聚合物的微电子器件（例如，作为异质结的一部分）。
• Phosphorus substituted metallocene compounds for olefin polymerization
  申请人：Voskoboynikov Z. Alexander

  公开号：US20050239980A1

  公开（公告）日：2005-10-27

  This invention relates to a metallocene compounds represented by formula: wherein M is a group 3, 4, 5 or 6 transition metal atom, or a lanthanide metal atom, or actinide metal atom; E is an indenyl ligand that is substituted with a PR 2 group in the two position of the indenyl ligand, where each R is, independently a hydrocarbyl, substituted hydrocarbyl, halocarbyl, or substituted halocarbyl substituent, and additionally, E may be substituted with 0, 1, 2, 3, 4, 5 or 6 R n where each R n is, independently, a hydrocarbyl, substituted hydrocarbyl, halocarbyl, substituted halocarbyl, silylcarbyl, substituted silylcarbyl, germylcarbyl, or substituted germylcarbyl substituent, and optionally, two or more adjacent R n substituents may join together to form a substituted or unsubstituted, saturated, partially unsaturated, or aromatic cyclic or polycyclic substituent; A is a substituted or unsubstituted cyclopentadienyl ligand, a substituted or unsubstituted heterocyclopentadienyl ligand, a substituted or unsubstituted indenyl ligand, a substituted or unsubstituted heteroindenyl ligand, a substituted or unsubstituted fluorenyl ligand, a substituted or unsubstituted heterofluorenyl ligand, or other mono-anionic ligand, or A may, independently, be defined as E or as X; each X is, independently, an univalent anionic ligand, or both X are joined and bound to the metal atom to form a metallocycle ring, or both X join to form a chelating ligand, a diene ligand, or an alkylidene ligand.

  本发明涉及一种由以下公式表示的金属茂化合物：其中M是3、4、5或6族过渡金属原子、镧系金属原子或锕系金属原子；E是一个在茂环的2位被PR2基取代的茚烯配体，其中每个R都是独立的，可以是一个碳氢化合物、取代的碳氢化合物、卤代碳氢化合物或取代的卤代碳氢化合物基团，此外，E可以被0、1、2、3、4、5或6个Rn取代，其中每个Rn都是独立的，可以是一个碳氢化合物、取代的碳氢化合物、卤代碳氢化合物、取代的卤代碳氢化合物、硅基碳氢化合物、取代的硅基碳氢化合物、锗基碳氢化合物或取代的锗基碳氢化合物基团，而且，两个或更多相邻的Rn取代基团可以结合在一起形成取代或未取代的饱和、部分不饱和或芳香环或多环取代基团；A是一个取代或未取代的环戊二烯基配体、取代或未取代的杂环戊二烯基配体、取代或未取代的茚烯配体、取代或未取代的杂茚烯配体、取代或未取代的芴基配体、取代或未取代的杂芴基配体或其他单阴离子配体，或者A可以独立地被定义为E或X；每个X都是独立的一价阴离子配体，或者两个X结合并与金属原子结合形成金属环烷基，或两个X结合形成螯合配体、二烯配体或烷基亚胺配体。
• Polyisocyanate curing agent and coating and adhesive cmpositions containing it
  申请人：NIPPON POLYURETHANE INDUSTRY CO. LTD.

  公开号：EP0495307A1

  公开（公告）日：1992-07-22

  A curing agent for a two-component polyurethane has as its main constituent a hexamethylene diisocyanate-derived polyisocyanate having a viscosity below 1,400 mPa.s/25°C substantially free from monomeric hexamethylene diisocyanate and from solvent, and having an uretidine dione dimer content of greater than 10% and an isocyanurate cyclic trimer content of less than 60%.

  一种用于双组分聚氨酯的固化剂，其主要成分是六亚甲基二异氰酸酯衍生的多异氰酸酯，其粘度低于 1,400 mPa.s/25°C，基本上不含六亚甲基二异氰酸酯单体和溶剂，尿苷二酮二聚体含量大于 10%，异氰尿酸酯环状三聚体含量小于 60%。
• Optically active diphosphines, intermediates thereof, and processes for production thereof
  申请人：MITSUI TOATSU CHEMICALS, Inc.

  公开号：EP0530015A1

  公开（公告）日：1993-03-03

  An optically active diphosphine having a bicyclo[2.2.1]heptane of the formula where R¹, R², R³ and R⁴ are defined in the specification, intermediates thereof and a metal complex comprising said optically active diphosphine are disclosed. A process for producing or purifying said optically active diphosphine is disclosed.

  一种光学活性二膦，其双环[2.2.1]庚烷的化学式为 其中 R¹、R²、R³ 和 R⁴ 在说明书中定义，本发明公开了其中间体和包含所述光学活性二膦的金属络合物。本发明还公开了一种生产或提纯所述光学活性二膦的工艺。
• Polyisocyanate curing agent and paint and adhesive compositions containing the same
  申请人：NIPPON POLYURETHANE INDUSTRY CO. LTD.

  公开号：EP0645411B1

  公开（公告）日：1997-12-29