bis(dimethylamido)diphenylgermane | 14103-75-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: bis(dimethylamido)diphenylgermane
• 英文别名: bis(dimethylamino)diphenylgermane；N-[dimethylamino(diphenyl)germyl]-N-methylmethanamine
• CAS: 14103-75-4
• 化学式: C₁₆H₂₂GeN₂
• 分子量: 314.954
• InChiKey: JWUGDAJKTHDQGG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.37
• 重原子数：
  19.0
• 可旋转键数：
  4.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.25
• 拓扑面积：
  6.48
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  水合氯醛 、 bis(dimethylamido)diphenylgermane 生成
  参考文献：
  名称：

  Barrau, Jacques; Rima, Ghassoub; Amine, Maria El, Journal of Chemical Research - Part S

  摘要：

  DOI：
• 作为产物：
  描述：

  四苯基锗 在 aluminum (III) chloride 作用下， 以 乙醚 为溶剂， 反应 9.0h， 生成 bis(dimethylamido)diphenylgermane
  参考文献：
  名称：

  仅含有吸电子取代基的低聚锗烷：合成与性能

  摘要：

  A series of germanes Ar3GeX, containing electron-withdrawing substituents [Ar = p-FC6H4, 1a-d, 1a (X = CO, 1b (X = Br), 1c (X = H), 1d (X = NMe2); p-F3CC6H4, 2a-d, 2a (X = Cl), 2b (X = Br), 2c (X = H), 2d (X = NMe2)], was synthesized and used to prepare symmetrical digermanes Ar3Ge-GeAr3, (p-FC6H4)(3)GeGe(C6H4F-p)(3) (3), and (p-F3CC6H4)(3)GeGe(C6H4CF3-p)(3) (4) and trigermane [(p-F3CC6H4)(3)Ge](2)Ge(C6F5)(2) (5) by hydrogermolysis reaction. The properties of all compounds were investigated by multinuclear NMR and for oligogermanes by UV/vis and fluorescence spectroscopy, as well as by electrochemical methods. In addition, the molecular structures of 1a, 1b, 2b, 2c, and 3-5 were studied by X-ray diffraction analysis. Compound 5 showed a significantly shifted UV/visible absorption to the red field in comparison with previously described derivatives.

  DOI：

  10.1021/acs.organomet.6b00767

文献信息

• Riviere-Baudet, Monique; Khallaayoun, Abdelhay; Morere, Alain, Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1990, vol. 20, p. 1317 - 1330
  作者：Riviere-Baudet, Monique、Khallaayoun, Abdelhay、Morere, Alain

  DOI：——

  日期：——
• RIVIERE-BAUDET, MONIQUE;KHALLAAYOUN, ABDELHAY;MORERE, ALAIN, SYNTH. AND REACT. INORG. AND METAL-ORG. CHEM., 20,(1990) N0, C. 1317-1330
  作者：RIVIERE-BAUDET, MONIQUE、KHALLAAYOUN, ABDELHAY、MORERE, ALAIN

  DOI：——

  日期：——
• BARRAU J.;RIMA G.;EL AMINE M.;SATGE J., J. CHEM. RES. SYNOP., 1985, N 1, 30-31
  作者：BARRAU J.、RIMA G.、EL AMINE M.、SATGE J.

  DOI：——

  日期：——