ethyl (3-thienylmercapto)acetate | 77151-56-5

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫醚类
• 英文名称: ethyl (3-thienylmercapto)acetate
• 英文别名: thienyl-3 thioglycolate d'ethyle；ethyl (3-thienothio)acetate；[3]thienylmercapto-acetic acid ethyl ester；[3]Thienylmercapto-essigsaeure-aethylester；2-(3-thienylthio)-acetic acid ethyl ester；ethyl 2-thiophen-3-ylsulfanylacetate
• CAS: 77151-56-5
• 化学式: C₈H₁₀O₂S₂
• 分子量: 202.298
• InChiKey: YAFZNNFLDOMMOF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  12
• 可旋转键数：
  5
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.38
• 拓扑面积：
  79.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  ethyl (3-thienylmercapto)acetate 在 ammonium hydroxide 作用下， 生成 2-thiophen-3-ylsulfanyl-acetamide
  参考文献：
  名称：

  Family Structure: Its Effects on Adolescent Attachment and Identity Formation

  摘要：

  This quantitative study examines the association between family structure, attachment, and identity formation. Results partially support the hypotheses and indicate that unresolved spouse conflict is associated with low levels of attachment in adolescents and attachment to father is linked to identity achieved and the diffused identity status. Lastly, parental coalition was inversely related to the moratorium and diffused identity statuses. These findings support a link between parent/adolescent relationships and the identity formation process. Directions for future research and clinical implications are also discussed.

  DOI：

  10.1080/01926180390201945
• 作为产物：
  描述：

  3-(carboxymethylsulfanyl)thiophene 、 乙醇 在 盐酸 作用下， 生成 ethyl (3-thienylmercapto)acetate
  参考文献：
  名称：

  Family Structure: Its Effects on Adolescent Attachment and Identity Formation

  摘要：

  This quantitative study examines the association between family structure, attachment, and identity formation. Results partially support the hypotheses and indicate that unresolved spouse conflict is associated with low levels of attachment in adolescents and attachment to father is linked to identity achieved and the diffused identity status. Lastly, parental coalition was inversely related to the moratorium and diffused identity statuses. These findings support a link between parent/adolescent relationships and the identity formation process. Directions for future research and clinical implications are also discussed.

  DOI：

  10.1080/01926180390201945

文献信息

• Chromium and Tungsten Carbene Complexes of Thieno[3,2-b]thiophene
  作者：Marilé Landman、Helmar Görls、Simon Lotz

  DOI：10.1002/1099-0682(20011)2001:1<233::aid-ejic233>3.0.co;2-q

  日期：2001.1

  appropriate metal carbonyl complex and subsequent alkylation with triethyloxonium tetrafluoroborate. Monocarbene [MC(OEt)T′T′H}(CO)5], (M = Cr, 1; W, 4), biscarbene [(CO)5MC(OEt)T′T′C(OEt)}M(CO)5], (M = Cr, 2; W, 5), and the products [MC(OEt)T′T′C(O)OEt} (CO)5], (M = Cr, 3; W, 6), where a metal moiety of 2 and 5 has been replaced by an ester functionality, were isolated. The reaction product afforded

  使用经典的 Fischer 方法制备了具有 3,6-二甲基噻吩并 [3,2-b] 噻吩 (T'T') 和噻吩并 [3,2-b] 噻吩 (TT) 间隔基的双核卡宾配合物。研究了它们在溶液中对氧的反应性以及它们的结构特征。铬和钨卡宾配合物是通过噻吩并噻吩的二锂化合成的，然后加入适当的金属羰基配合物，然后用四氟硼酸三乙基氧鎓进行烷基化。单卡宾 [MC(OEt)T'T'H}(CO)5], (M = Cr, 1; W, 4), 双卡宾 [(CO)5MC(OEt)T'T'C(OEt) )}M(CO)5], (M = Cr, 2; W, 5), 以及乘积 [MC(OEt)T'T'C(O)OEt} (CO)5], (M = Cr, 3; W, 6)，其中 2 和 5 的金属部分已被酯官能团取代，被分离出来。Cr(CO)6 与锂化噻吩[3,
• Synthesis, photochromic and fluorescent properties of hybrid compounds of fulgimides and benzothiazolylthienothiophene
  作者：L. K. Karabaeva、I. A. Platonova、I. V. Zavarzin、S. I. Luiksaar、V. N. Yarovenko、B. V. Nabatov、M. M. Krayushkin、V. A. Barachevski

  DOI：10.1007/s10593-011-0745-9

  日期：2011.5

  The precursors and hybrid compounds, including photochromic fulgimides and fluorescent benzothiazolylthienothiophene units, have been synthesized. Spectroscopic investigations by absorption and fluorescence methods showed that fulgimide hybrids display photochromism, but do not display fluorescence properties. A possible explanation for this fact is proposed and also the decreased effectiveness of photochromic conversion.
• Paulmier, Claude; Outurquin, Francis, Journal of Heterocyclic Chemistry, 1983, vol. 20, p. 113 - 119
  作者：Paulmier, Claude、Outurquin, Francis

  DOI：——

  日期：——
• PAULMIER, C.;OUTURQUIN, F., J. HETEROCYCL. CHEM., 1983, 20, N 1, 113-119
  作者：PAULMIER, C.、OUTURQUIN, F.

  DOI：——

  日期：——