copper(II) complex of 1,8-bis(3-benzoyl-2-ethyl-isoureido)-3,6-dioxaoctane | 365999-29-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: copper(II) complex of 1,8-bis(3-benzoyl-2-ethyl-isoureido)-3,6-dioxaoctane
• 英文别名: Kupfer(II) Komplex von 1,8-Bis(3-benzoyl-2-ethyl-isoureido)-3,6-dioxaoctan
• CAS: 365999-29-7
• 化学式: C₂₆H₃₂CuN₄O₆
• 分子量: 560.109
• InChiKey: GTSHKCLJENONKZ-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  1,8-bis(3-benzoyl-2-ethyl-isoureido)-3,6-dioxaoctane 、 copper(II) acetate monohydrate 以 甲醇 为溶剂， 以86%的产率得到copper(II) complex of 1,8-bis(3-benzoyl-2-ethyl-isoureido)-3,6-dioxaoctane
  参考文献：
  名称：

  Mononukleare Kupfer(II)-Komplexe von dioxaalkylenund alkylenverbrückten Bis-isoharnstoffen

  摘要：

  By reaction of N-benzoylthiocarbamic-O,S-diethyl-ester with primary diamines (oxa)alkylene bridged isoureas I have been prepared. They yield with Cu-II neutral chelates 2 with tetradentate ligand coordination. The structures of the ligand 1a and of the related Cu-II complex 2 a have been determined by X-ray crystal structure analysis. They show an enamine tautomer in the ligand and a slightly tetrahedrally distorted coordination with an (oxa)alkylene bridge between the trans arranged N ligator atoms in the complex.

  DOI：

  10.1002/1521-3749(200108)627:8<1877::aid-zaac1877>3.0.co;2-x