1,4-bis(5-(benzylidenehydrazineylidene)-4-phenyl-4,5-dihydro-1,3,4-thiadiazol-2-yl)benzene | 1367775-52-7

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,4-bis(5-(benzylidenehydrazineylidene)-4-phenyl-4,5-dihydro-1,3,4-thiadiazol-2-yl)benzene
• CAS: 1367775-52-7
• 化学式: C₃₆H₂₆N₈S₂
• 分子量: 634.788
• InChiKey: GWIIPNIIJPLUDY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.38
• 重原子数：
  46.0
• 可旋转键数：
  8.0
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  85.08
• 氢给体数：
  0.0
• 氢受体数：
  10.0

反应信息

• 作为产物：
  描述：

  4-[N,N'-diphenyl(bis(hydrazonoyldichlorides))]benzene 在 盐酸 作用下， 以 水 、 N,N-二甲基甲酰胺 为溶剂， 反应 18.0h， 生成 1,4-bis(5-(benzylidenehydrazineylidene)-4-phenyl-4,5-dihydro-1,3,4-thiadiazol-2-yl)benzene
  参考文献：
  名称：

  Synthesis of 1,3,4-thiadiazines, bis-1,3,4-thiadiazoles, [1,2,4]triazino[3,4-b][1,3,4]thiadiazine, thiazolines from carbonothioic dihydrazide

  摘要：

  A novel and efficient synthesis of 1,3,4-thiadiazines, bis-1,3,4-thiadiazoles, [1,2,4]triazino[3,4-b][1,3,4] thiadiazine, and thiazolines is reported from the reaction of alpha-haloketo hydrazonoyl halides with carbonothioic dihydrazide or its analogues. The structures were elucidated on the basis of their elemental analysis, spectral data and an alternative synthetic route. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.tet.2012.02.011

文献信息

• Synthesis of 1,3,4-thiadiazines, bis-1,3,4-thiadiazoles, [1,2,4]triazino[3,4-b][1,3,4]thiadiazine, thiazolines from carbonothioic dihydrazide
  作者：Abdelwahed R. Sayed

  DOI：10.1016/j.tet.2012.02.011

  日期：2012.4

  A novel and efficient synthesis of 1,3,4-thiadiazines, bis-1,3,4-thiadiazoles, [1,2,4]triazino[3,4-b][1,3,4] thiadiazine, and thiazolines is reported from the reaction of alpha-haloketo hydrazonoyl halides with carbonothioic dihydrazide or its analogues. The structures were elucidated on the basis of their elemental analysis, spectral data and an alternative synthetic route. (C) 2012 Elsevier Ltd. All rights reserved.