C60 fullerene | 118425-85-7

• 分子结构分类: 有机化合物
• 英文名称: C60 fullerene
• 英文别名: pristine
• CAS: 118425-85-7
• 化学式: C₆₀
• 分子量: 720.66
• InChiKey: NEBFLSUJAYZFPO-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.88
• 重原子数：
  60.0
• 可旋转键数：
  0.0
• 环数：
  32.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0.0
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为反应物：
  描述：

  叠氮化钾 、 C60 fullerene 以 neat (no solvent, gas phase) 为溶剂， 生成
  参考文献：
  名称：

  Conduction-electron spin resonance in the superconductorK3C60

  摘要：

  The conduction-electron spin resonance of the superconducting fulleride compound, K3C60 (T-c = 19 K) has been observed between 2.5 and 800 K at several frequencies from 9 to 225 GHz. Between T-c and 0.7T(c) the spin lifetime of normal excitations increases as predicted by the theory of Yafet for scattering from nonmagnetic structural defects. At lower temperatures the CESR arises from states bound to vortices; here the spectrum is inhomogeneously broadened and an anomalous g shift is found. The anomalous temperature dependence of the g factor and linewidth in the normal state reported by Petit et al. is most important between 50 and 250 K, suggesting that these are related to the rotation of C-60 ions.

  DOI：

  10.1103/physrevb.61.7118

文献信息

• Structures and magnetic properties of high-temperature reaction products of cerium metal and C60 solid
  作者：Y Maruyama、S Motohashi、K Suzuki、S Takagi、H Ogata

  DOI：10.1016/s0038-1098(00)00232-5

  日期：2000.7

  Abstract Structures and magnetic properties of high temperature reaction products of Ce metal and C60 solid have been investigated by means of X-ray diffraction and SQUID magnetometory. The X-ray diffraction patterns of relatively low temperature products show that they seem to undergo metal–ion-intercalation to C60 crystals. Unusual behaviors in the temperature dependence of the magnetization of the

  摘要 利用X射线衍射和SQUID磁强计研究了Ce金属与C60固体的高温反应产物的结构和磁性能。相对低温产物的 X 射线衍射图表明它们似乎经历了金属离子嵌入 C60 晶体。产品磁化温度依赖性的异常行为揭示了铁磁性和反磁性（超导）性质的共存或竞争，其发生取决于反应温度和时间。