tetraphenylantimony nicotinate | 741687-04-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: tetraphenylantimony nicotinate
• 英文别名: (tetraphenyl-λ5-stibanyl) pyridine-3-carboxylate
• CAS: 741687-04-7
• 化学式: C₃₀H₂₄NO₂Sb
• 分子量: 552.276
• InChiKey: WIBKTEKAFXCKCU-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  3.77
• 重原子数：
  34
• 可旋转键数：
  7
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  39.2
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  pentaphenylantimony 、 bis(nicotinato)(triphenyl)antimony(V) 以 苯 为溶剂， 以91%的产率得到tetraphenylantimony nicotinate
  参考文献：
  名称：

  Synthesis and Structure of Tetraphenylantimony Nicotinate

  摘要：

  Tetraphenylantimony nicotinate was prepared in 91% yield by reaction of pentaphenylantimony with triphenyl antimony bis(nicotinate) in toluene. Triphenylantimony bis(nicotinate), in turn, was prepared in 87% yield by oxidative addition of pyridine-3-carboxylic acid to triphenylstibine in ether in the presence of hydrogen peroxide. The structure of tetraphenyl antimony nicotinate was determined by single-crystal X-ray diffraction. The Sb atom has a distorted trigonal bipyramidal coordination surrounding with the carboxy group in the axial position. The Sb-C distances are 2.118(1), 2.121(1), 2.130(1), and 2.170(1) Angstrom, and the Sb-O distance is 2.268(1) Angstrom. There is an intramolecular contact between the Sb atom and the carbonyl O atom [3.363(1) Angstrom].

  DOI：

  10.1023/b:rugc.0000025501.29625.ff