diacetyl monooxime anthraniloylhydrazone | 952190-59-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: diacetyl monooxime anthraniloylhydrazone
• 英文别名: Biacetylmonoxime-o-aminobenzoylhydrazone；2-amino-N-(3-hydroxyiminobutan-2-ylideneamino)benzamide
• CAS: 952190-59-9
• 化学式: C₁₁H₁₄N₄O₂
• 分子量: 234.258
• InChiKey: XYBIIZUCLSQZMF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  17
• 可旋转键数：
  3
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.18
• 拓扑面积：
  100
• 氢给体数：
  3
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  锌 、 diacetyl monooxime anthraniloylhydrazone 在 N(C₂H₅)3 作用下， 以 甲醇 为溶剂， 以62%的产率得到Zn(diacetyl monooxime anthraniloylhydrazone(1-))2
  参考文献：
  名称：

  Crystal engineering with aroyl hydrazones of diacetyl monooxime – Molecular and supramolecular structures of two Ni(II) and two Zn(II) complexes

  摘要：

  Four new Schiff bases of aroyl hydrazides with diacetyl monooxime have been prepared, and Ni(II) and Zn(II) complexes of these ligands have been synthesized. Two Ni(II) and two Zn(II) complexes have been characterized by X-ray crystallography. The aroyl hydrazone ligands were designed in such a way that there is a systematic variation in the H-bond forming abilities of their aroyl moiety, e.g. both H-bond acceptor and donor (salicyloyl), only H-bond donor (anthraniloyl), only H-bond acceptor (isonicotinoyl). It is shown in this work that such a variation in the H-bond donor acceptor properties of the ligands leads to considerable diversity in their supramolecular architecture. (c) 2007 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2007.03.063