N,N-di-p-tolyl-3-vinylaniline | 1239277-76-9

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: N,N-di-p-tolyl-3-vinylaniline
• 英文别名: 3-ethenyl-N,N-bis(4-methylphenyl)aniline
• CAS: 1239277-76-9
• 化学式: C₂₂H₂₁N
• 分子量: 299.415
• InChiKey: HQXXBJIGBWQLMX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.7
• 重原子数：
  23
• 可旋转键数：
  4
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.09
• 拓扑面积：
  3.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  3-溴苯乙烯 、 4,4'-二甲基二苯胺 在 bis(dibenzylideneacetone)-palladium⁽⁰⁾ 、 sodium t-butanolate 、 tri tert-butylphosphoniumtetrafluoroborate 作用下， 以 甲苯 为溶剂， 以85%的产率得到N,N-di-p-tolyl-3-vinylaniline
  参考文献：
  名称：

  RAFT法制备含苯并噻二唑的侧链聚合物及其电光性能

  摘要：

  报道了一系列新型的，不对称取代的含苯并噻二唑的乙烯基单体的合成及其在有无可逆加成-断裂链转移（RAFT）剂控制下的自由基聚合。所得的具有电活性侧基的聚合物显示出可调节的吸收和发射光谱，这取决于它们的分子结构。使用RAFT允许使用空穴传输性乙烯基三芳基胺作为第二单体来合成嵌段共聚物。已检测到两个吊坠之间的有效能量传递。空气测量中的循环伏安法和光电子能谱法已用于揭示嵌段共聚物的HOMO和LUMO的位置。

  DOI：

  10.1021/ma1008572

文献信息

• ORGANIC ELECTRONIC DEVICE
  申请人：LECLOUX DANIEL DAVID

  公开号：US20080138655A1

  公开（公告）日：2008-06-12

  There is provided an active layer containing a dopant material and a host material, wherein the host material has an HPLC purity of at least 99.9% and an impurity absorbance no greater than 0.01. There is also provided an electronic device containing the active layer.

  提供了一种含有掺杂材料和主体材料的活性层，其中主体材料的高效液相色谱纯度至少为99.9％，杂质吸光度不大于0.01。还提供了一种包含该活性层的电子器件。
• Compositions comprising novel copolymers and electronic devices made with such compositions
  申请人：Radu Sabina Nora

  公开号：US20070228364A1

  公开（公告）日：2007-10-04

  The present invention relates to novel copolymers, compositions comprising novel copolymers, and electronic devices comprising at least one layer containing the copolymer.
• HOLE TRANSPORT POLYMERS
  申请人：Radu Sabina Nora

  公开号：US20080097076A1

  公开（公告）日：2008-04-24

  Cross-linkable hole transport polymers comprising at least one first monomer comprised of an arylamine and at least one second monomer comprised of a fluorene, carbazole, diphenylsilicon or fused heterocyclic derivative are provided. In some embodiments, the hole transport polymers also comprise at least one third monomer, different from the second monomer, and comprised of a fluorene, carbazole, diphenylsilicon or fused heterocyclic derivative. Electronic devices made with the polymeric materials are also provided.
• PROCESS FOR FORMING AN ORGANIC LIGHT-EMITTING DIODE AND DEVICES MADE BY THE PROCESS
  申请人：Prakash Shiva

  公开号：US20080166566A1

  公开（公告）日：2008-07-10

  There is provided a new process for forming a light-emitting diode device having first, second, and third subpixel areas. In the process a hole injection layer is applied over an anode layer. The hole injection material has a conductive polymer and a fluorinated acid polymer. A hole transport layer is applied over the hole injection layer. A first electroluminescent material which is either green or red, is applied to the first subpixel areas. A second electroluminescent material which is either red or green, is applied to the second subpixel areas. A blue electroluminescent material is applied overall, followed by deposition of a cathode. The second electroluminescent material emits a color different from that of the first electroluminescent material.
• HOLE TRANSPORT COMPOSITION
  申请人：E I DU PONT DE NEMOURS AND COMPANY

  公开号：US20130150536A1

  公开（公告）日：2013-06-13

  There is provided a hole transport composition having (i) a first hole transport polymer having crosslinkable groups, and (ii) a second hole transport polymer having substantially no crosslinkable groups. There is also provided a crosslinked hole transport layer and an electronic device containing the crosslinked hole transport layer.