2-(Octadecyloxy)-1,3,2-benzodoxaphosphole | 101748-87-2

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: 2-(Octadecyloxy)-1,3,2-benzodoxaphosphole
• 英文别名: 2-Octadecoxy-1,3,2-benzodioxaphosphole
• CAS: 101748-87-2
• 化学式: C₂₄H₄₁O₃P
• 分子量: 408.562
• InChiKey: NYRKDKOUCXTCDI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.6
• 重原子数：
  28
• 可旋转键数：
  18
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  27.7
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  a-丙烯酸氯甲酯 、 硬脂醇 生成 2-(Octadecyloxy)-1,3,2-benzodoxaphosphole
  参考文献：
  名称：

  Techniques for postcolumn derivatization in gas chromatography/mass spectrometry

  摘要：

  The connection of the output of a conventional split-type capillary GC (gas chromatography) injector to the region between a capillary gas chromatograph and a mass spectrometer has allowed the addition of reagents to this region for purposes of postcolumn derivatization. This combination delivers very narrow spikes of reagent which are scavenged very efficiently. Derivatizations on a peak by peak basis are easily accomplished. The derivatization reactions must proceed at or near the ambient GC oven temperature and at atmospheric pressure. In addition the reactions must be complete in less than 1 s. Bromination, deuterium exchange, and a variety of acylation reactions have been demonstrated.

  DOI：

  10.1021/ac00003a013

文献信息

• LIGON, WOODFIN V. (JR);GRADE, HANS, ANAL. CHEM., 63,(1991) N, C. 255-261
  作者：LIGON, WOODFIN V. (JR)、GRADE, HANS

  DOI：——

  日期：——