[(C6H4CH2P(1-adamantyl)2)Pt(p-FC6H4)(pyridine)] | 1239698-94-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [(C6H4CH2P(1-adamantyl)2)Pt(p-FC6H4)(pyridine)]
• CAS: 1239698-94-2
• 化学式: C₃₈H₄₅FNPPt
• 分子量: 760.834
• InChiKey: MUTQMFDRVAJQMQ-ZSDQVAMVSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为反应物：
  描述：

  二氟代氙 、 [(C6H4CH2P(1-adamantyl)2)Pt(p-FC6H4)(pyridine)] 以 二氯甲烷 为溶剂， 以92%的产率得到[(C6H4CH2P(1-adamantyl)2)Pt(p-C6H4F)(pyridine)F2]
  参考文献：
  名称：

  Reagent-Dependent Formation of C−C and C−F Bonds in Pt Complexes: An Unexpected Twist in the Electrophilic Fluorination Chemistry

  摘要：

  Cyclometalated platinum(II) complexes (C-P)Rt(Aryl)py undergo oxidative addition reaction upon treatment with electrophilic fluorination reagents, XeF(2) or N-fluoro-2,4,6-trimethylpyridinium tetrafluoroborate, giving eventually products of C-C coupling. However, when aryl = mesityl, the two reagents give completely different products: the N-F salt still favors the C-C coupling reaction while XeF(2) gives the unprecedented benzylic fluorination of one of the ortho-methyl groups of the mesityl ligand.

  DOI：

  10.1021/ja101436w
• 作为产物：
  描述：

  吡啶 、 [(C6H4CH2P(1-adamantyl)2)PtCl]2 、 4-氟苯基溴化镁 以 四氢呋喃 为溶剂， 生成 [(C6H4CH2P(1-adamantyl)2)Pt(p-FC6H4)(pyridine)]
  参考文献：
  名称：

  Reagent-Dependent Formation of C−C and C−F Bonds in Pt Complexes: An Unexpected Twist in the Electrophilic Fluorination Chemistry

  摘要：

  Cyclometalated platinum(II) complexes (C-P)Rt(Aryl)py undergo oxidative addition reaction upon treatment with electrophilic fluorination reagents, XeF(2) or N-fluoro-2,4,6-trimethylpyridinium tetrafluoroborate, giving eventually products of C-C coupling. However, when aryl = mesityl, the two reagents give completely different products: the N-F salt still favors the C-C coupling reaction while XeF(2) gives the unprecedented benzylic fluorination of one of the ortho-methyl groups of the mesityl ligand.

  DOI：

  10.1021/ja101436w