2,8-dimethyl-10-phenylphenoxaphosphine 10-oxide | 21990-63-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,8-dimethyl-10-phenylphenoxaphosphine 10-oxide
• 英文别名: 2,8-dimethyl-10-phenylphenoxaphosphinine 10-oxide；2,8-Dimethyl-10-phenylphenoxaphosphin-10-oxid；2,8-dimethyl-10-phenyl-10H-phenoxaphosphine 10-oxide
• CAS: 21990-63-6
• 化学式: C₂₀H₁₇O₂P
• 分子量: 320.328
• InChiKey: ZQKIIFYNCUGQST-UHFFFAOYSA-N

物化性质

• 熔点：
  191-192 °C
• 沸点：
  525.943±50.00 °C(Press: 760.00 Torr)(predicted)
• 密度：
  1.260±0.10 g/cm3(Temp: 25 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.4
• 重原子数：
  23
• 可旋转键数：
  1
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.1
• 拓扑面积：
  26.3
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  2,8-dimethyl-10-phenylphenoxaphosphine 10-oxide 在 三氯硅烷 作用下， 以 苯 为溶剂， 生成 2,8-Dimethyl-10-phenylphenoxaphosphin
  参考文献：
  名称：

  Granoth,I. et al., Israel Journal of Chemistry, 1968, vol. 6, p. 651 - 657

  摘要：

  DOI：
• 作为产物：
  描述：

  苯基二氯化磷 在 aluminum (III) chloride 、 双氧水 作用下， 以 溶剂黄146 为溶剂， 反应 9.0h， 生成 2,8-dimethyl-10-phenylphenoxaphosphine 10-oxide
  参考文献：
  名称：

  Phosphorus-containing copolyesters: The effect of ionic group and its analogous phosphorus heterocycles on their flame-retardant and anti-dripping performances

  摘要：

  A series of copolyesters containing ionic groups (PETIs-K) were synthesized by melt co-polycondensation using terephthalic acid, ethylene glycol, and potassium salt of bishydroxyethyl ester of 10-hydroxy-10-oxo-10H-phenoxaphosphine-2,8-dicarboxylic acid (DHPPO-K) as monomers. The copolyesters only with analogous phosphorus-containing heterocycles (PETPs) were also synthesized and used as a control. The dynamic rheological behaviors confirmed that the complex viscosity of PETIs-K increased with increasing temperature due to the existence of ionic aggregates, which restricted melt dripping, while PETPs had flow behaviors similar to PET: the complex viscosity decreased with increasing temperature. The ionic groups induced the decomposition of the polymer backbone to form a more stable residue at high temperatures, which made PETIs-K exhibit good flame retardancy even with low phosphorus contents. Cone test showed the peak heat release rate and total smoke production of PETP5 decreased to 34% and 58% of pure PET. Compared with PETP5, these values for PETI5-K were reduced by 31% and 50%, respectively. EDX and ICP-AES results demonstrated that 92% of phosphorus for PETI10-K remained in char residues; however, this value for PETP10 was only 45%. Combined with results of XPS, Raman spectroscopy and Py-GC/MS, it can be proved that the ionization of phosphorus took main effects in condensed phase via promoting carbonization to form stable graphitic char, which avoided the decrease of carbonization due to the competitive effects of phosphorus in gas phase. (C) 2015 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.polymer.2015.01.030

文献信息

• Direct Synthesis of Dibenzophospholes from Biaryls by Double C–P Bond Formation via Phosphenium Dication Equivalents
  作者：Kazutoshi Nishimura、Koji Hirano、Masahiro Miura

  DOI：10.1021/acs.orglett.0c00944

  日期：2020.4.17

  the generation of phosphenium dication equivalents from readily available phosphinic acids and Tf2O. The in situ-generated dication equivalents can be readily coupled with simple (hetero)biaryls to form the corresponding dibenzophospholes directly. This protocol can also be applied to the concise synthesis of six- and seven-membered phosphacycles as well as the largely π-extended heteroacene derivatives

  我们已经开发了一种新的策略，用于从易于获得的次膦酸和Tf 2 O生成正当当量。原位生成的正当当量可轻松与简单的（杂）联芳基偶合，直接形成相应的二苯并膦。该方案也可用于六元和七元磷环的简捷合成以及大部分π延伸的杂并苯衍生物，这些在有机功能材料领域非常重要。
• ORGANIC LIGHT-EMITTING DEVICE
  申请人：SAMSUNG DISPLAY CO., LTD.

  公开号：US20170244048A1

  公开（公告）日：2017-08-24

  An organic light-emitting device including: a first electrode; a second electrode facing the first electrode; and an organic layer between the first electrode and the second electrode and including an emission layer, wherein the organic layer includes: i) a hole transport region between the first electrode and the emission layer, and including at least one selected from a hole injection layer, a hole transport layer, an emission auxiliary layer, and an electron blocking layer, and ii) an electron transport region between the emission layer and the second electrode and including an electron transport layer, in addition to at least one selected from a hole blocking layer, an electron control layer, a buffer layer, and an electron injection layer, wherein the electron transport region includes a compound represented by Formula 1:

  一种有机发光器件，包括：第一电极；面向第一电极的第二电极；以及位于第一电极和第二电极之间的有机层，其中包括一个发射层，所述有机层包括：i）在第一电极和发射层之间的空穴传输区，包括至少从空穴注入层、空穴传输层、发射辅助层和电子阻挡层中选择的一种及以上；和ii）在发射层和第二电极之间的电子传输区，包括一个电子传输层，除了至少从阻挡层、电子控制层、缓冲层和电子注入层中选择的一种及以上，其中电子传输区包括由式子1表示的化合物：