(2-(4-tert-butyl-2-pyridyl)phenyl)chloromercury | 267241-69-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: (2-(4-tert-butyl-2-pyridyl)phenyl)chloromercury
• CAS: 267241-69-0
• 化学式: C₁₅H₁₆ClHgN
• 分子量: 446.342
• InChiKey: UHZGHNYVNGKFKX-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.85
• 重原子数：
  18
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.27
• 拓扑面积：
  12.9
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  (2-(4-tert-butyl-2-pyridyl)phenyl)chloromercury 以 二氯甲烷 、 乙腈 为溶剂， 生成 diacetato(2-(4-tert-butyl-2-pyridyl)phenyl)gold(III)
  参考文献：
  名称：

  Mercury(II) and gold(III) derivatives of 2-phenyl pyridines and 2-phenyl-4-(methylcarboxylato)quinoline

  摘要：

  ortho-Mercurated derivatives of several substituted 2-phenylpyridines and of 2-phenyl-4-(methylcarboxylato)quinoline have been prepared and characterised. C,N-chelated gold(III) derivatives, [AuCl2(C6H4C5H3RN)] (R = H, 3-Me, 3,5-Me-2, 4-Pr-n, 4-Bu-t) are prepared more efficiently by trans-metallation reactions than by direct reaction of AuCl4- with the phenylpyridines. The new gold complexes were characterised spectroscopically and a variety of substitution reactions have been effected. As is usual with unsymmetrical bidentate ligands, the softer donor atom is found trans to the N-donor of the pyridine unit. Crystal-structure determinations are reported for [Au(OAc)(pmpy)(py)]ClO4, [Au(ppy)(dpbt)]BPh4, [Au(ppy)(S2CNMe2)]BPh4 and AuCl(pqcm)(2) [Hppy = 2-phenylpyridine, Hpmpy = 2-phenyl-3-methylpyridine, Hpqcm = 2-phenyl-4-(methylcarboxylato)quinoline]. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00645-2
• 作为产物：
  描述：

  4 -(1,1-二甲基乙基)- 2 -苯基吡啶 、 mercury(II) diacetate 、 lithium chloride 以 甲醇 、 乙醇 为溶剂， 生成 (2-(4-tert-butyl-2-pyridyl)phenyl)chloromercury
  参考文献：
  名称：

  Mercury(II) and gold(III) derivatives of 2-phenyl pyridines and 2-phenyl-4-(methylcarboxylato)quinoline

  摘要：

  ortho-Mercurated derivatives of several substituted 2-phenylpyridines and of 2-phenyl-4-(methylcarboxylato)quinoline have been prepared and characterised. C,N-chelated gold(III) derivatives, [AuCl2(C6H4C5H3RN)] (R = H, 3-Me, 3,5-Me-2, 4-Pr-n, 4-Bu-t) are prepared more efficiently by trans-metallation reactions than by direct reaction of AuCl4- with the phenylpyridines. The new gold complexes were characterised spectroscopically and a variety of substitution reactions have been effected. As is usual with unsymmetrical bidentate ligands, the softer donor atom is found trans to the N-donor of the pyridine unit. Crystal-structure determinations are reported for [Au(OAc)(pmpy)(py)]ClO4, [Au(ppy)(dpbt)]BPh4, [Au(ppy)(S2CNMe2)]BPh4 and AuCl(pqcm)(2) [Hppy = 2-phenylpyridine, Hpmpy = 2-phenyl-3-methylpyridine, Hpqcm = 2-phenyl-4-(methylcarboxylato)quinoline]. (C) 2000 Elsevier Science S.A. All rights reserved.

  DOI：

  10.1016/s0022-328x(99)00645-2

文献信息

• Mercury(II) and gold(III) derivatives of 2-phenyl pyridines and 2-phenyl-4-(methylcarboxylato)quinoline
  作者：R.V Parish、Jonathan P Wright、Robin G Pritchard

  DOI：10.1016/s0022-328x(99)00645-2

  日期：2000.2

  ortho-Mercurated derivatives of several substituted 2-phenylpyridines and of 2-phenyl-4-(methylcarboxylato)quinoline have been prepared and characterised. C,N-chelated gold(III) derivatives, [AuCl2(C6H4C5H3RN)] (R = H, 3-Me, 3,5-Me-2, 4-Pr-n, 4-Bu-t) are prepared more efficiently by trans-metallation reactions than by direct reaction of AuCl4- with the phenylpyridines. The new gold complexes were characterised spectroscopically and a variety of substitution reactions have been effected. As is usual with unsymmetrical bidentate ligands, the softer donor atom is found trans to the N-donor of the pyridine unit. Crystal-structure determinations are reported for [Au(OAc)(pmpy)(py)]ClO4, [Au(ppy)(dpbt)]BPh4, [Au(ppy)(S2CNMe2)]BPh4 and AuCl(pqcm)(2) [Hppy = 2-phenylpyridine, Hpmpy = 2-phenyl-3-methylpyridine, Hpqcm = 2-phenyl-4-(methylcarboxylato)quinoline]. (C) 2000 Elsevier Science S.A. All rights reserved.