bis[N-(4'-benzo-15-crown-5)-2-(amino-N-tosyl)-phenylaldimine]zinc | 916676-16-9

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: bis[N-(4'-benzo-15-crown-5)-2-(amino-N-tosyl)-phenylaldimine]zinc
• 英文别名: zinc N-(4'-benzo-15-crown-5)-2-(amino-N-tosyl)phenylaldiminate；[(4-(2-tosylaminobenzal)aminobenzo-15-crown-5(-1H))2Zn]
• CAS: 916676-16-9
• 化学式: C₅₆H₆₂N₄O₁₄S₂Zn
• 分子量: 1144.65
• InChiKey: CTOHYULQVPGXNT-DEBRICFFSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  bis[N-(4'-benzo-15-crown-5)-2-(amino-N-tosyl)-phenylaldimine]zinc 、 potassium thioacyanate 以 乙腈 为溶剂， 生成 KSCN*[zinc N-(4'-benzo-15-crown-5)-2-(amino-N-tosyl)phenylaldiminate]*H2O
  参考文献：
  名称：

  Zinc N-(4′-benzo-15-crown-5)-2-(amino-N-tosyl)phenylaldiminate: Complexation and ion-selective properties

  摘要：

  The lithium, sodium, and potassium complexes with zinc N-(4'-benzo-15-crown-5)-2-(amino-N-tosyl)phenylaldiminate (ZnL2) have been synthesized. Their IR spectra have been studied, and selected vibrational frequencies of the ligand and complexes have been assigned. Based on spectroscopy and elemental analysis data, the structure of the complexes has been suggested. The ion-selective properties of ZnL2 have been studied by potentiometry.

  DOI：

  10.1134/s0036023607110125
• 作为产物：
  描述：

  4'-[2-(tosylamino)benzylideneamino]-2,3-benzo-15-crown-5 、 zinc diacetate 以 甲醇 为溶剂， 生成 bis[N-(4'-benzo-15-crown-5)-2-(amino-N-tosyl)-phenylaldimine]zinc
  参考文献：
  名称：

  Zn complex with N-(4′-Benzo-15-crown-5)-2-(amino-N-tosyl)-phenylaldimine: Synthesis, crystal structure, and vibration spectrum

  摘要：

  The ZnL2 complex (I) (HL = N-(4'-benzo-15-crown-5)-2-(amino-N-tosyl)phenylaldimine) is synthesized and studied by IR spectroscopy and X-ray diffraction analysis. The crystals are monoclinic: a = 23.139(2) angstrom. b = 19.931(2) angstrom, c = 14.604(2) angstrom. beta = 121.20(1)degrees. Z = 4. space group C2/c. R = 0.751 tor 766 reflections with l > 2 sigma(l). The Zn atom in a molecule of the complex lies on a twofold axis and is coordinated at the vertices of a distorted tetrahedron by four N atoms of two HL ligands (average Zn-N distance 2.024 angstrom).

  DOI：

  10.1134/s107032840603002x

文献信息

• Complexing properties of ambidentate benzo-15-crown-5-substituted azomethine ligands
  作者：A. S. Burlov、A. V. Tsukanov、G. S. Borodkin、Yu. V. Revinskii、A. D. Dubonosov、V. A. Bren’、A. D. Garnovskii、A. Yu. Tsivadze、V. I. Minkin

  DOI：10.1134/s1070363206060259

  日期：2006.6

  Crown-containing azomethines and their zinc complexes were prepared. Examination of their structure by H-1 and Li-7 NMR and electronic spectroscopy showed that, in accordance with the concept of hard and soft acids and bases, the hard lithium cation coordinates to the crown ether fragment with the formation of mono- (Li) and binuclear (Li, Zn) complexes.