| 16920-83-5

• 分子结构分类: 有机化合物
• CAS: 16920-83-5
• 化学式: C₄H₁₂Cl₄S₂Ti
• 分子量: 313.963
• InChiKey: LGVVXTLRODJFIO-UHFFFAOYSA-J

反应信息

• 作为产物：
  描述：

  二甲基硫 、 四氯化钛 以 二氯甲烷 为溶剂， 以98%的产率得到
  参考文献：
  名称：

  四氯化钛与有机硫化合物的加合物。TiCl 4（C 4 H 8 S）2和（TiCl 4）2（CH 3 SSCH 3）的晶体和分子结构

  摘要：

  用一系列有机硫醇处理四氯化钛可得到TiCl 4（HSR）2式的加合物，收率为77–89％。四氯化钛与有机硫化物的反应生成了TiCl 4（SR 2）2式的硫化物加合物，产率为87-98％。这些配合物是易挥发的，并且具有顺式-有机硫配体。用二硫化甲基处理四氯化钛可得到加合物（TiCl 4）2（CH 3 SSCH 3），产率为98％，采用具有Ti 2 Cl 8核和桥联二硫配体的双核结构。TiCl的晶体结构测定了4（C 4 H 8 S）2和（TiCl 4）2（CH 3 SSCH 3）。讨论了这些观察结果与二硫化钛和三硫化钛薄膜化学气相沉积的关系。

  DOI：

  10.1016/s0277-5387(97)00309-4

文献信息

• Adducts of titanium tetrahalides with neutral Lewis bases. Part I. Structure and stability: a vibrational and multinuclear NMR study
  作者：Eric Turin、Roger M. Nielson、André E. Merbach

  DOI：10.1016/s0020-1693(00)84458-8

  日期：1987.11
• Electron density redistribution on complexation in non-transition element complexes
  作者：O.Kh. Poleshchuk、B. Nogaj、G.N. Dolenko、V.P. Elin

  DOI：10.1016/0022-2860(93)80185-x

  日期：1993.8

  Complexes of tin, antimony, silicon, germanium, iodine, boron and titanium halogenides with organic ligands were investigated using nuclear quadrupole resonance (NQR) and X-ray fluorescence spectroscopies, and Mossbauer effect and quantum-chemical calculations. A discussion of results which we obtained previously as well as literature data is included. The correlations between Cl-35 NQR and ClKalpha line shifts in SnCl4L2, SbCl5L and TiCl4L2 complexes were obtained. The geometry of the acceptor was found to influence the value of the effective charge on the chlorine atom (q(Cl)) in SnCl4L2 complexes, but not to influence the chlorine atom in TiCl4L2 complexes. Values of q(Sn) and q(Sb) were calculated from Mossbauer isomer shifts in the SnCl4L2 and SbCl5L complexes. Electron-density transfer from the ligand to the vacant d orbital of the central atom on complexation was observed.
• Dolenko; Poleshchuk; Gostevskii, Russian Journal of Coordination Chemistry, 1999, vol. 25, # 10, p. 744 - 747
  作者：Dolenko、Poleshchuk、Gostevskii、Latoshinska、Ostafin

  DOI：——

  日期：——