10-(4-formylphenyl)-6b,7,8,9,9a,10-hexahydro[g]cyclopenta[b]indole | 1416133-86-2

• 分子结构分类: 有机化合物 - 有机氮化合物
• 英文名称: 10-(4-formylphenyl)-6b,7,8,9,9a,10-hexahydro[g]cyclopenta[b]indole
• CAS: 1416133-86-2
• 化学式: C₁₈H₁₇NO
• 分子量: 263.339
• InChiKey: WIHNKFWPGGAYAT-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.29
• 重原子数：
  20.0
• 可旋转键数：
  2.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.28
• 拓扑面积：
  20.31
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  、 10-(4-formylphenyl)-6b,7,8,9,9a,10-hexahydro[g]cyclopenta[b]indole 在 哌啶 作用下， 以 正丁醇 为溶剂， 反应 4.0h， 以69%的产率得到C₃₇H₃₇N₅O₄S₂
  参考文献：
  名称：

  Application of novel N-(p-phenylene)-dicyanovinylidene double rhodanine indoline dye for zinc oxide dye-sensitized solar cell

  摘要：

  A new indoline dye in which a double rhodanine acceptor is attached to the indoline moiety by a p-phenylene spacer on the indoline-nitrogen, has been examined for its performance as a sensitizer for zinc oxide dye-sensitized solar cells. In the presence of cholic acid, chenodeoxycholic acid, or lithocholic acid: the performance was greatest for lithocholic acid as this showed the greatest reduction in dye H-aggregate formation. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2012.08.023
• 作为产物：
  描述：

  1,2,3,3a,4,8b-六氢环戊二烯并[b]吲哚 、 对溴苯甲醛 在 2-双环己基膦-2',6'-二甲氧基联苯 、 palladium diacetate 、 sodium t-butanolate 作用下， 以 甲苯 为溶剂， 以31%的产率得到10-(4-formylphenyl)-6b,7,8,9,9a,10-hexahydro[g]cyclopenta[b]indole
  参考文献：
  名称：

  Application of novel N-(p-phenylene)-dicyanovinylidene double rhodanine indoline dye for zinc oxide dye-sensitized solar cell

  摘要：

  A new indoline dye in which a double rhodanine acceptor is attached to the indoline moiety by a p-phenylene spacer on the indoline-nitrogen, has been examined for its performance as a sensitizer for zinc oxide dye-sensitized solar cells. In the presence of cholic acid, chenodeoxycholic acid, or lithocholic acid: the performance was greatest for lithocholic acid as this showed the greatest reduction in dye H-aggregate formation. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.dyepig.2012.08.023