2-[[2-(Benzylamino)phenyl]diazenyl]-5-chlorophenol | 1454894-01-9

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2-[[2-(Benzylamino)phenyl]diazenyl]-5-chlorophenol
• CAS: 1454894-01-9
• 化学式: C₁₉H₁₆ClN₃O
• 分子量: 337.809
• InChiKey: WBTATJGZJOUGQA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.4
• 重原子数：
  24
• 可旋转键数：
  5
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  57
• 氢给体数：
  2
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  sodium tetrachloropalladate(II) 、 2-[[2-(Benzylamino)phenyl]diazenyl]-5-chlorophenol 以 甲醇 为溶剂， 反应 12.0h， 以60%的产率得到
  参考文献：
  名称：

  Tetranuclear assembly of palladium(II): Catalyst for C–C coupling reactions

  摘要：

  The 2-((2-benzylamino)phenyldiazenyl)phenol, H2OL [where H2OL = ArOHN = NC6H4N(H)CH2(C6H5); Ar = C6H5 (for H2OL1). P-MeC6H4 (for H2OL2) or p-ClC6H4 (for H2OL3)], ligands were prepared by the reaction of the appropriate 2-((2-hydroxyaryl)azo)anilines with benzyl bromide. The reactions of Na2PdCl4 with H2OL afforded tetranuclear Pd(II) complexes of the composition [pd(OL)](4). The ligands bind palladium(II) in a tridentate (N, N, O) fashion. The X-ray structure of [Pd(OL1)](4) was determined to confirm the characterization. The newly synthesized [Pd(OL1)](4) complex was utilized as a catalyst for the Suzuki and Heck reaction for a variety of substrates. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.07.020
• 作为产物：
  描述：

  2-((2-amino phenyl)diazenyl) 5-chlorophenol 、 溴甲苯 在 吡啶 、 potassium iodide 作用下， 以 乙腈 为溶剂， 反应 10.0h， 以50%的产率得到2-[[2-(Benzylamino)phenyl]diazenyl]-5-chlorophenol
  参考文献：
  名称：

  Tetranuclear assembly of palladium(II): Catalyst for C–C coupling reactions

  摘要：

  The 2-((2-benzylamino)phenyldiazenyl)phenol, H2OL [where H2OL = ArOHN = NC6H4N(H)CH2(C6H5); Ar = C6H5 (for H2OL1). P-MeC6H4 (for H2OL2) or p-ClC6H4 (for H2OL3)], ligands were prepared by the reaction of the appropriate 2-((2-hydroxyaryl)azo)anilines with benzyl bromide. The reactions of Na2PdCl4 with H2OL afforded tetranuclear Pd(II) complexes of the composition [pd(OL)](4). The ligands bind palladium(II) in a tridentate (N, N, O) fashion. The X-ray structure of [Pd(OL1)](4) was determined to confirm the characterization. The newly synthesized [Pd(OL1)](4) complex was utilized as a catalyst for the Suzuki and Heck reaction for a variety of substrates. (C) 2013 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2013.07.020