Cu(II) complex of centro-(methyl)(benzyloxy)-capped Dioxocyclam*CH2Cl2 | 287411-44-3

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 大环内酰胺类
• 英文名称: Cu(II) complex of centro-(methyl)(benzyloxy)-capped Dioxocyclam*CH2Cl2
• CAS: 287411-44-3
• 化学式: CH₂Cl₂*C₃₇H₄₇N₅O₄*Cu
• 分子量: 774.29
• InChiKey: PRSJSOOXORSXRF-SYUCMZJMSA-L

反应信息

• 作为产物：
  描述：

  copper(II) tetrafluroborate hexahydrate 、 pyridine-capped centro-(methyl)(benzyloxy)dioxocyclam 在 K₂CO₃ 作用下， 以 二氯甲烷 为溶剂， 生成 Cu(II) complex of centro-(methyl)(benzyloxy)-capped Dioxocyclam 、 Cu(II) complex of centro-(methyl)(benzyloxy)-capped Dioxocyclam*CH2Cl2
  参考文献：
  名称：

  Synthesis and Structural Studies of 1,8-Pyridine-Capped 5,12-Dioxocyclams

  摘要：

  5,12-Dioxocyclams and bis-dioxocyclams were capped across the 1,8-secondary amino groups with 2,6-bis(bromomethyl)pyridine to give pyridine-capped mono- and bis-dioxocyclams. The copper(II) complex of capped monocyclam 5b was prepared and characterized by X-ray crystallography. Treatment of dioxocyclams with 2,3,5,6-tetrakis(bromomethyl)pyrazine produced bis-cyclams connected through the ir secondary amino groups through the 2,3- and 5,6-positions of the pyrazine.

  DOI：

  10.1021/ja994352l