Cu(malonato)(pyridine)(H2O) | 287488-15-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: Cu(malonato)(pyridine)(H2O)
• CAS: 287488-15-7
• 化学式: C₃H₂O₄*C₅H₅N*Cd*H₂O
• 分子量: 311.573
• InChiKey: IPEMRBREWSIJFN-UHFFFAOYSA-L

反应信息

• 作为产物：
  描述：

  吡啶 、 丙二酸 、 cadmium(II) sulfate*8/3H2O 在 NaOH 作用下， 以 水 为溶剂， 以92%的产率得到Cu(malonato)(pyridine)(H2O)
  参考文献：
  名称：

  Microporous networks co-assembled by both rigid and flexible building blocks

  摘要：

  The porous networks of [Cu-2(malonato)(2)(bipy) (H2O)(2)] . H2O (I) and [Cd(malonato)(py)(H2O)] (II) were co-assembled by rigid 4,4'-bipyridine or pyridine and the flexible malonate: ion. In the network of compound I, 4,4'-bipy acts as a bone, separating and supporting the flexible malonate-Cu units to form a nearly strain-free square framework and a chiral square cavity in the solid state. In compound II, the rigid pyridine rings sustain the network by saturating the coordination sphere of Cd(II) ion to avoid a high coordination number and self-inclusion, and to prevent the two-dimensional network from forming a non-porous phase. (C) 2000 Elsevier Science Ltd All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00361-2