[Cu(4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole)2(MeCO2)2(H2O)2] | 1095815-09-0

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [Cu(4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole)2(MeCO2)2(H2O)2]
• CAS: 1095815-09-0
• 化学式: C₂₈H₃₀CuN₁₂O₆
• 分子量: 694.169
• InChiKey: BJAICZROYQUSFP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  水 、 copper(II) acetate monohydrate 、 双(吡啶-3-基)-4H-1,2,4-三唑-4-胺 以 甲醇 、 水 为溶剂， 以30%的产率得到[Cu(4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole)2(MeCO2)2(H2O)2]
  参考文献：
  名称：

  Syntheses, structures and thermal stabilities of four complexes with 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole ligand

  摘要：

  Reactions of 4-amino-3,5-bis(3-pyridyl)-1,2,4-triazole (3-abpt) with metal acetates gave rise to four new complexes [Cu(3-abpt)(ip)](n) center dot 2nH(2)O (1), [Co(3-abpt)(ip)(H2O)(2)](n)center dot 2nH(2)O (2), [Ni(3-abpt)(tp)(H2O)(2)](n) (3) and [Cu(3-abpt)(2)(CH3COO)(2)(H2O)(2)] (4) (ip = isophthalate, tp = terephthalate), which were characterized by EA, IR and X-ray crystallography. Compound I consists of two kinds of ring-like chain which are interconnected to form an unusual two-dimensional layered motif. Compounds 2 and 3 are both I D ring-like infinite chains. Compound 4 is a mononuclear complex. The thermal stabilities of coordination polymers 1-3 have been investigated. (c) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.molstruc.2008.03.011