| 148448-37-7

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• CAS: 148448-37-7
• 化学式: C₂₇H₂₄Cl₃FeN₄O₃
• 分子量: 614.719
• InChiKey: NBBOJKSCKMTSHG-RVHXFTGPSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  、 三氯化铁 在 KOH 作用下， 以 乙腈 为溶剂， 以74%的产率得到
  参考文献：
  名称：

  Mono- and tetra-nuclear manganese(III) complexes of tripodal tris[2-(salicylideneamino)ethyl]amines

  摘要：

  The tripodal ligands N[CH2CH2N=CHC6H3X(OH)-2]3 (X = H, H-3L1 or Cl-5, H-3L2] afford the mononuclear complexes [Mn(III)L]. Structural work has shown that the symmetry of the facial MnN3O3 co-ordination sphere in the two solvates [MnL2].3H2O and [MnL2].MeOH varies considerably as the former has C3 and the latter C1 symmetry. The implications of these differences are discussed. Reaction of [MnL] with manganese(III) acetate dihydrate in alkaline media affords the antiferromagnetic tetranuclear cations [MnIII4O2L2]2+ in high yields. X-Ray studies on [Mn4O2L12][PF6]2.4MeCN have revealed a centrosymmetric Mn4(mu3-O)28+ core, with the shortest Mn...Mn contact being 2.906(3) angstrom. The metal co-ordination spheres are of two types: facial-MnN3O3 and MnNO5. The cyclic voltammograms of [Mn4O2L2]2+ display two successive waves due to the Mn(III)-Mn(II) couples of the MnN3O3 spheres. For [MnL] only one such couple is observed. Oxidative responses due to Mn(IV)-Mn(III) couples are also observed. Some preliminary work on an iron(III) analogue of [Mn4O2L2]2+ is also described.

  DOI：

  10.1039/dt9930000863
• 作为产物：
  描述：

  iron(II) perchlorate hexahydrate 、 tris(2-((5-chlorosalicylidene)amino)ethyl)amine 在 KOH 作用下， 以 乙腈 为溶剂， 以76%的产率得到
  参考文献：
  名称：

  Mono- and tetra-nuclear manganese(III) complexes of tripodal tris[2-(salicylideneamino)ethyl]amines

  摘要：

  The tripodal ligands N[CH2CH2N=CHC6H3X(OH)-2]3 (X = H, H-3L1 or Cl-5, H-3L2] afford the mononuclear complexes [Mn(III)L]. Structural work has shown that the symmetry of the facial MnN3O3 co-ordination sphere in the two solvates [MnL2].3H2O and [MnL2].MeOH varies considerably as the former has C3 and the latter C1 symmetry. The implications of these differences are discussed. Reaction of [MnL] with manganese(III) acetate dihydrate in alkaline media affords the antiferromagnetic tetranuclear cations [MnIII4O2L2]2+ in high yields. X-Ray studies on [Mn4O2L12][PF6]2.4MeCN have revealed a centrosymmetric Mn4(mu3-O)28+ core, with the shortest Mn...Mn contact being 2.906(3) angstrom. The metal co-ordination spheres are of two types: facial-MnN3O3 and MnNO5. The cyclic voltammograms of [Mn4O2L2]2+ display two successive waves due to the Mn(III)-Mn(II) couples of the MnN3O3 spheres. For [MnL] only one such couple is observed. Oxidative responses due to Mn(IV)-Mn(III) couples are also observed. Some preliminary work on an iron(III) analogue of [Mn4O2L2]2+ is also described.

  DOI：

  10.1039/dt9930000863