| 1201478-53-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 茚和异茚
• CAS: 1201478-53-6
• 化学式: C₂₆H₂₂MnN₂O₈
• 分子量: 545.407
• InChiKey: YGBVIMFFHMANAF-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  BI-LAWSONE 、 manganese (II) acetate tetrahydrate 、 N,N-二甲基甲酰胺 以 水 、 N,N-二甲基甲酰胺 为溶剂， 生成
  参考文献：
  名称：

  Solvent control on the structural versatility and properties of manganese(II) complexes surrounded by the flexible hinge-like ligand

  摘要：

  Four different types of polynuclear manganese(II) compounds with bhnq(2-) bridges were obtained from the reaction of Mn(CH3COO)(2)center dot 4H(2)O with the flexible hinge-like ligand H(2)bhnq (H(2)bhnq =2,2'-bi(3-hydroxy-1,4-naphthoquinone)) by controlling the reaction solvent: [Mn-3(bhnq)(3)(H2O)2]center dot 10.5H(2)O (1). [Mn-2(bhnq)(2) (DMSO)(4)]center dot 2DMSO center dot CHCl3 (2), {[Mn(bhnq)(H2O)2]center dot 2H(2)O}(n) (3), and {[Mn(bhnq)(DMF)(2)]}(n) (4). All complexes are neutral with the same Mn/bhnq 1:1 formulation ratio. Compounds 1 and 2 are discrete systems, while compounds 3 and 4 are one-dimensional ones. All compounds were characterized by X-ray diffraction and show different coordination modes for the bhnq(2-) ligand. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2010.03.007