α-methylstyrene 4-sulfonic acid | 89642-98-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: α-methylstyrene 4-sulfonic acid
• 英文别名: 4-isopropenyl-benzenesulfonic acid；4-Isopropenyl-benzolsulfonsaeure；4-Prop-1-en-2-ylbenzenesulfonic acid
• CAS: 89642-98-8
• 化学式: C₉H₁₀O₃S
• 分子量: 198.243
• InChiKey: LNIRBSSUMJWSBZ-UHFFFAOYSA-N

物化性质

• 密度：
  1.254±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.1
• 重原子数：
  13
• 可旋转键数：
  2
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.11
• 拓扑面积：
  62.8
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  α-methylstyrene 4-sulfonic acid 、 丙烯腈 在 硫酸 作用下， 反应 6.0h， 以96.5%的产率得到
  参考文献：
  名称：

  一种丙烯酰胺类单体及其制备方法和应用

  摘要：

  本发明公开了一种丙烯酰胺类单体及其制备方法和应用，其中，该单体具有式（1）所示的结构，其中，R1为C1‑C8的烷基，R2为氢或C1‑C4的烷基，M1和M2各自独立地为氢、钾和钠中的至少一种。实验表明该单体进行聚合得到的丙烯酰胺共聚物具有较高的分子量和优异的耐温抗盐性能和耐剪切性能，可以作为高温高盐油藏三次采油驱油剂。

  公开号：

  CN104628611B
• 作为产物：
  描述：

  ALFA, ALFA-二甲基苄氯 、 硫酸 生成 α-methylstyrene 4-sulfonic acid
  参考文献：
  名称：

  NICU, M., BUL. INST. POLITEHN. IASI, 1981, 27, N 3-4, 109-116

  摘要：

  DOI：

文献信息

• POSITIVE-TYPE RESIST COMPOSITION, METHOD FOR FORMING RESIST PATTERN, PHOTO-REACTIVE QUENCHER, AND POLYMERIC COMPOUND
  申请人：TOKYO OHKA KOGYO CO., LTD.

  公开号：US20160376233A1

  公开（公告）日：2016-12-29

  A positive-type resist composition which generates an acid upon exposure and whose solubility in an alkali developing solution increases under the action of an acid, the composition including a base material component whose solubility in an alkali developing solution increases under the action of an acid; and a compound represented by the following general formula (m0): Z 01 to Z 04 each independently represent a substituent having electron withdrawing properties, Rb 21 and Rb 22 each independently represent an alkyl group, an alicyclic hydrocarbon group which may have a substituent, or a hydroxyl group, Rb 1 represents an aryl group which may have a substituent, an alkyl group, or an alkenyl group, n1 and n2 represent an integer of 0 to 3, and X0 − represents an organic anion.

  一种正型抗蚀组合物，曝光后生成酸，其在碱性显影溶液中的溶解度在酸的作用下增加，该组合物包括一种基材组分，在酸的作用下在碱性显影溶液中的溶解度增加；以及由以下一般式（m0）表示的化合物：Z01至Z04分别独立表示具有电子吸引性的取代基，Rb21和Rb22分别独立表示烷基基团、可能具有取代基的脂环烃基团或羟基，Rb1表示可能具有取代基的芳基、烷基或烯基，n1和n2表示0至3的整数，X0−表示有机阴离子。
• Composition for forming polishing pad, crosslinked body for polishing pad, polishing pad using the same and method for producing thereof
  申请人：JSR Corporation

  公开号：EP1201368A2

  公开（公告）日：2002-05-02

  It is an object of the invention to provide a composition for forming a polishing pad comprising substances having specific functional groups exhibiting excellent hydrophilic properties and the like, a crosslinked body for polishing pad as well as a polishing pad with excellent water resisting and durability which exhibits excellent polishing performance including a high removal rate and method for producing thereof. The composition for forming a polishing pad comprises a crosslinkable elastomer having no carboxyl, amino, hydroxyl, epoxy, sulfonic acid and phosphoric acid groups, and a water-insoluble substance having at least one functional group selected from the group consisting of carboxyl, amino, hydroxyl, epoxy, sulfonic acid and phosphoric acid groups. And a water-soluble substance such as cyclodextrin may be contained. A polishing pad can be manufactured using the composition above or the crosslinked body for polishing pad, and porous polishing pads may also be obtained.

  本发明的目的是提供一种用于形成抛光垫的组合物，该组合物由具有特定官能团的物质组成，这些官能团具有优异的亲水性等特性，还提供一种用于抛光垫的交联体以及一种具有优异防水性和耐久性的抛光垫，该抛光垫具有优异的抛光性能，包括高去除率及其生产方法。用于形成抛光垫的组合物包括不含羧基、氨基、羟基、环氧基、磺酸基和磷酸基的可交联弹性体，以及至少具有一个选自羧基、氨基、羟基、环氧基、磺酸基和磷酸基的官能团的水不溶性物质。还可以含有环糊精等水溶性物质。使用上述组合物或用于抛光垫的交联体可以制造出抛光垫，还可以获得多孔抛光垫。
• Reaction product of aqueous copolymer emulsion and polyvalent metal compound and polishing composition containing same
  申请人：JSR Corporation

  公开号：EP1396507A1

  公开（公告）日：2004-03-10

  A reaction product of (I) an aqueous emulsion of a copolymer of (a) 5-50 wt% of an ethylenically unsaturated carboxylic acid monomer and/or the salt thereof, (b) 0.05-20 wt% of ethylenically unsaturated sulfonic acid monomer and/or the salt thereof, and (c) other ethylenically unsaturated monomers polymerizable with the monomers (a) and (b), provided that the total of monomers (a), (b), and (c) is 100 wt%, the copolymer having a Tg from -30°C to +20°C, and (II) a polyvalent metal compound. The reaction product is useful as a floor polish excelling in durability, adhesion to substrates, and recoatability that are well balanced with removability with an alkali, and decreased TVOC due to absence or low content of a low boiling point coalescent agent and plasticizer.

  以下物质的反应产物：(I) 共聚物的水乳液：(a) 5-50 wt%的乙烯基不饱和羧酸单体和/或其盐，(b) 0.05-20重量％的乙烯基不饱和磺酸单体和/或其盐，和(c)可与单体(a)和(b)聚合的其它乙烯基不饱和单体，条件是单体(a)、(b)和(c)的总和为100重量％，共聚物的Tg为-30℃至+20℃，和(II)多价金属化合物。该反应产物可用作地板上光剂，在耐久性、对基材的附着力和重涂性方面表现出色，并能很好地平衡碱的去除性，以及由于不含或少含低沸点凝聚剂和增塑剂而降低的 TVOC。
• Ink set for ink-jet recording and ink-jet recording method
  申请人：FUJIFILM Corporation

  公开号：EP1840177A1

  公开（公告）日：2007-10-03

  The present invention is an ink set for ink-jet recording including at least one first liquid A for forming at least an image and at least one second liquid B different in composition from the above first liquid A, wherein at least the liquid A contains a polymerizing or crosslinking material, and wherein any one liquid of at least the liquids A and B contains a triarylsulfonium salt polymerization initiator having one or more of aryl backbones having an electron-accepting group as a substituent.

  本发明是一种用于喷墨记录的墨水组，包括至少一种用于形成至少一个图像的第一液体A和至少一种在成分上不同于上述第一液体A的第二液体B，其中至少液体A含有聚合或交联材料，并且至少液体A和B中的任何一种液体含有三芳基锍盐聚合引发剂，该引发剂具有一个或多个以电子接受基团为取代基的芳基骨架。
• VINYL ALCOHOL-BASED GRAFT POLYMER, METHOD FOR PRODUCING SAME, AND ION-EXCHANGE MEMBRANE USING SAME
  申请人：Kuraray Co., Ltd.

  公开号：EP2930193A1

  公开（公告）日：2015-10-14

  Provided are (1) a vinyl alcohol graft copolymer grafting polymerizable unsaturated monomers as a graft chain onto a side-chain mercapto group-containing vinyl alcohol polymer backbone, the graft chain being attached to the polymer backbone at a mercapto group, and the backbone including: a vinyl alcohol unit and a unit represented by the following formula (I): wherein R1 is a hydrogen atom or a carboxyl group; R2 is a hydrogen atom, a methyl group, a carboxyl group, or a carboxymethyl group; and X is a divalent C1-22 group which contains a carbon atom and a hydrogen atom and may contain a nitrogen atom and/or an oxygen atom; and (2) an ion-exchange membrane having controlled swelling in water and excellent flex resistance, the membrane including a vinyl alcohol graft copolymer as described above.

  提供了(1)一种乙烯醇接枝共聚物，将可聚合的不饱和单体作为接枝链接枝到含有侧链巯基的乙烯醇聚合物骨架上，接枝链在巯基处连接到聚合物骨架上，骨架包括：乙烯醇单元和由下式(I)表示的单元： 其中 R1 是氢原子或羧基；R2 是氢原子、甲基、羧基或羧甲基；X 是二价 C1-22 基团，该基团含有一个碳原子和一个氢原子，并可能含有一个氮原子和/或一个氧原子；以及 (2) 一种离子交换膜，该膜具有可控的水中溶胀性和优异的抗弯曲性，该膜包括上述乙烯醇接枝共聚物。