1,6-Bis-(p-aminophenyl)hexane | 3491-14-3

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 1,6-Bis-(p-aminophenyl)hexane
• 英文别名: 1.6-Bis-(4-amino-phenyl)-hexan；1,6-Bis(p-aminophenyl)hexane；4-[6-(4-aminophenyl)hexyl]aniline
• CAS: 3491-14-3
• 化学式: C₁₈H₂₄N₂
• mdl: MFCD00155343
• 分子量: 268.402
• InChiKey: XLKGPJIGDHZIMW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.1
• 重原子数：
  20
• 可旋转键数：
  7
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  52
• 氢给体数：
  2
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  1,6-Bis-(p-aminophenyl)hexane 、 N-acetyl-2-imidazolone 生成 1-[2-[4-[6-[4-[(1-acetyl-4,5-dihydroimidazol-2-yl)amino]phenyl]hexyl]anilino]-4,5-dihydroimidazol-1-yl]ethanone
  参考文献：
  名称：

  摘要：

  DOI：
• 作为产物：
  描述：

  N-乙酰苯胺 在 sodium hydroxide 、 三氯化铝 、 一水合肼 作用下， 反应 2.0h， 生成 1,6-Bis-(p-aminophenyl)hexane
  参考文献：
  名称：

  Loewe; Urbanietz, Arzneimittel-Forschung/Drug Research, 1965, vol. 15, # 6, p. 604 - 608

  摘要：

  DOI：

文献信息

• PROCESS FOR MAKING BENZOXAZINES
  申请人：Cytec Industries Inc.

  公开号：US20160115139A1

  公开（公告）日：2016-04-28

  A synthesis process for making a benzoxazine compound containing at least one benzoxazine unit from aromatic amine containing at least one primary amino group, at least one phenolic compound with at least one ortho-hydrogen, and alkyl formcel. In one embodiment, the aromatic amine is reacted with alkyl formcel to generate an alkoxymethyl intermediate compound. Subsequently, the intermediate compound is reacted with a phenol to generate the benzoxazine compound. In another embodiment, the benzoxazine compound is formed by reacting aromatic amine with alkyl formcel and phenol in one reaction step. Also disclosed is a method for isolating the alkoxymethyl compound formed by reacting aromatic amine with alkyl formcel. The isolated alkoxymethyl compound is useful as a reactant in a subsequent reaction.

  一种合成过程，用于从含有至少一个苯并噁嗪单元的芳香胺，至少含有一个一级氨基的芳香胺，至少含有一个邻位氢的酚类化合物和烷基甲醛制备含有至少一个苯并噁嗪单元的苯并噁嗪化合物。在一种实施方式中，将芳香胺与烷基甲醛反应以生成烷氧甲基中间体化合物。随后，将中间体化合物与酚反应以生成苯并噁嗪化合物。在另一种实施方式中，通过在一个反应步骤中将芳香胺与烷基甲醛和酚反应来形成苯并噁嗪化合物。还公开了一种方法，用于分离由芳香胺与烷基甲醛反应形成的烷氧甲基化合物。分离的烷氧甲基化合物可用作随后反应中的反应物。
• Inkjet ink
  申请人：Satou Hiroyuki

  公开号：US20080085361A1

  公开（公告）日：2008-04-10

  The invention relates to a method for manufacturing an inkjet ink including a polyamic acid (A), including a step of at least reacting one or more compounds selected from the group of a monoamine (a3) and a compound having one acid anhydride group (a4) with a compound having two or more acid anhydride groups (a1) and a diamine (a2).

  该发明涉及一种制造喷墨墨水的方法，包括至少将来自单胺（a3）和具有一个酸酐基团（a4）的化合物组合的群体中选择的一个或多个化合物与具有两个或更多酸酐基团（a1）和二胺（a2）反应的聚酰胺酸（A）。
• Liquid-Crystal Aligning Agent, Liquid-Crystal Alignment Film Comprising the Same, and Liquid-Crystal Element
  申请人：Tsutsui Kimiaki

  公开号：US20070224370A1

  公开（公告）日：2007-09-27

  It is to provide a liquid crystal aligning agent capable of forming a liquid crystal alignment film having favorable electrical characteristics, and excellent in the storage stability and the productivity. A liquid crystal aligning agent comprising at least one member selected from a polyamic acid obtained by polymerization of a diamine component with a tetracarboxylic dianhydride component, and a polyimide obtained by cyclodehydration of the polyamic acid, characterized in that the diamine component contains at least one of diamines represented by the following formula [1]: H 2 N-A-R—NH 2 [1] wherein A is a bivalent organic group comprising a benzene ring or an aromatic condensed ring, provided that one or more optional hydrogen atoms in the benzene ring or the aromatic condensed ring may be substituted by a monovalent organic group other than an amino group, and R is a C 1-10 bivalent saturated hydrocarbon group.

  本发明旨在提供一种液晶取向剂，能够形成具有良好电学特性、储存稳定性和生产率优异的液晶取向膜。液晶取向剂包括至少一种由二胺组分与四羧酸二酐组分聚合得到的聚酰胺酸和由聚酰胺酸环状脱水得到的聚酰亚胺，其特征在于二胺组分中包含下式[1]所表示的二胺之一：H2N-A-R—NH2[1]其中，A是一个双价的有机基团，包括苯环或芳香环，并且苯环或芳香环中的一个或多个可选氢原子可以被除氨基以外的一价有机基团取代，R是一个C1-10双价饱和碳氢基团。
• Bis-imidazolinoamino derivatives as useful antiallergy compounds
  申请人：USV PHARMACEUTICAL CORPORATION

  公开号：EP0187989A1

  公开（公告）日：1986-07-23

  Compounds of the formula: and pharmaceutically acceptable salts thereof; wherein Ar, is phenyl, naphthyl, or a nitrogen, oxygen or sulfur heterocyclic ring; X and Y are independently O, S or a chemical bond; Z, and Z3 are each a chemical bond or alkylene chain containing up to 6 carbon atoms in the principal chain and up to a total of 10 carbon atoms; Z2 and Z4 are each chemical bond, alkylene chain containing up to 6 carbon atoms in the principal chain and a total of up to 10 carbon atoms, aryl, cycloalkyl, or a nitrogen, oxygen, sulfur heterocyclic ring; each R, is independently hydrogen, lower alkyl, aryl, lower aralkyl, hydroxy, lower alkoxy, carboxy, lower carbalkoxy, lower carbaralkoxy, lower carbaryloxy, lower alkoxy carbonyl, lower alkanoyl, cyano, halogen, amino loweralkylmercapto, lower alkenyl, lower alkynyl, lowercycloalkyl. R2, R5, R7, R9 and R13 are independently hydrogen, lower alkyl or lower alkanoyl; but when the nitrogen to which R2 is attached contains a double bond, then R2 is -, when the nitrogen to which R9 is attached contains a double bond, then R9 is-, or when the nitrogen to which R,3 is attached contains a double bond, then R,3 is-; then R,3 is -; R3, R4, R6 and R8 are independently hydrogen, lower alkyl, cyano, or nitro; R11 and R,2 are independently hydrogen, or lower alkyl; n is 0, 1, 2, or 3 and m is 0, 1, or 2; provided that when Z2 is a chemical bond or methylene group, X and Y cannot be toth oxygen or sulfur simul- taneousty.

  式化合物 及其药学上可接受的盐； 其中 Ar 是苯基、萘基或氮、氧或硫杂环； X 和 Y 独立地为 O、S 或化学键 Z和Z3各自是化学键或亚烷基链，在主链中最多含有6个碳原子，总共最多含有10个碳原子； Z2和Z4各自是化学键、主链中最多含有6个碳原子且总共最多含有10个碳原子的亚烷基链、芳基、环烷基或氮、氧、硫杂环； 每个 R 独立地是氢、低级烷基、芳基、低级芳烷基、羟基、低级烷氧基、羧基、低级碳烷氧基、低级碳烷氧基、低级碳酰氧基、低级烷氧基羰基、低级烷酰基、氰基、卤素、氨基、低级烷巯基、低级烯基、低级炔基、低级环烷基。 R2、R5、R7、R9 和 R13 独立地为氢、低级烷基或低级烷酰基；但当 R2 所连接的氮含有双键时，则 当 R2 所连接的氮含有双键时，R2 为-；当 R9 所连接的氮含有双键时，R9 为-；或当 R,3 所连接的氮含有双键时，R,3 为-；则 R,3 为-； R3、R4、R6 和 R8 独立地为氢、低级烷基、氰基或硝基； R11 和 R,2 独立地为氢或低级烷基； n 是 0、1、2 或 3，以及 m 为 0、1 或 2； 但当 Z2 是化学键或亚甲基时，X 和 Y 不能是氧或硫的同素异形体。
• Toughened thermosetting structural materials
  申请人：CYTEC TECHNOLOGY CORP.

  公开号：EP0377194A2

  公开（公告）日：1990-07-11

  The incorporation of 2 to 25 µm particles of a limited class of polyimides having appreciable nonaromatic character into heat curable epoxy resin systems significantly increases the toughness of such systems without loss of other desirable properties. These toughened epoxy resin systems are useful in preparing carbon fiber reinforced composites having compression strength after impact (CAI) of greater than 45 Ksi after a 1500 in-lb/in impact.

  在热固化环氧树脂体系中加入 2 至 25 µm 的具有明显非芳香族特性的有限类别的聚酰亚胺颗粒，可显著提高此类体系的韧性，而不会损失其他理想特性。这些增韧环氧树脂体系可用于制备碳纤维增强复合材料，在受到 1500 英寸-磅/英寸冲击后，其冲击后压缩强度（CAI）大于 45 Ksi。