4-(N,N-Dibenzylamino)-2-phenylbut-1-ene | 101219-25-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-(N,N-Dibenzylamino)-2-phenylbut-1-ene
• 英文别名: 4-(Dibenzylamino)-2-phenyl-1-butene；N,N-dibenzyl-3-phenylbut-3-en-1-amine；1-dibenzylamino-3-phenylbut-3-ene
• CAS: 101219-25-4
• 化学式: C₂₄H₂₅N
• 分子量: 327.469
• InChiKey: AIHLVKGXUVTIIO-UHFFFAOYSA-N

物化性质

• 沸点：
  450.9±34.0 °C(Predicted)
• 密度：
  1.044±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.79
• 重原子数：
  25.0
• 可旋转键数：
  8.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.17
• 拓扑面积：
  3.24
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  4-(N,N-Dibenzylamino)-2-phenylbut-1-ene 以13%的产率得到
  参考文献：
  名称：

  AOYAMA, HIROMU;ARATA, YOSHIAKI;OMOTE, YOSHIMORI, J. CHEM. SOC. CHEM. COMMUN., 1985, N 20, 1381-1382

  摘要：

  DOI：
• 作为产物：
  描述：

  二苄胺 在 三乙胺 作用下， 生成 4-(N,N-Dibenzylamino)-2-phenylbut-1-ene
  参考文献：
  名称：

  AMINE-FUNCTIONAL MONOMERS AND METHODS OF MAKING SAME

  摘要：

  Disclosed herein are addition-polymerizable monomer composition including an amine-derivatized alpha-methyl styrene (ADAMS) monomer according to structure (I) and/or an aminated conjugated aliphatic methylated polyene (ACAMP) monomer according to structure (II): with k, R 1 , R 2 , R 3 , and R 4 defined herein. Difunctional monomers of these types with two polymerizable loci and/or two amine loci are also disclosed herein. Further disclosed herein are methods for making such compositions.

  公开号：

  US20240287009A1

文献信息

• Photocyclisation of γ,δ- and δ, ε-unsaturated amines. Hydrogen transfer reactions via eight-membered cyclic transition states
  作者：Hiromu Aoyama、Yoshiaki Arata、Yoshimori Omote

  DOI：10.1039/c39850001381

  日期：——

  Photolysis 4-(N,N-dibenzylamino)-2-phenylbut-1-ene and 5-(N,N-dibenzylamino)-2-phenylpent-1-ene gave cyclisation products via 1,6- and 1,7-hydrogen shifts respectively.

  4-（N，N-二苄氨基）-2-苯基丁-1-烯和5-（N，N-二苄氨基）-2-苯基戊-1-烯的光解通过1,6-和1,7-氢产生环化产物分别移动。
• Palladium-Catalyzed Vinylation of Aminals with Simple Alkenes: A New Strategy To Construct Allylamines
  作者：Yinjun Xie、Jianhua Hu、Yanyu Wang、Chungu Xia、Hanmin Huang

  DOI：10.1021/ja310848x

  日期：2012.12.26

  A novel, highly selective palladium-catalyzed vinylation reaction for the direct synthesis of allylic amines from styrenes and aminals has been established. The utility of this method was also demonstrated by the rapid synthesis of cinnarizine from aldehydes, amines, and simple alkenes in one-pot manner. Mechanistic studies suggested that the reaction proceeds through a valuable cyclometalated Pd(II) complex generated by the oxidative addition of aminal to a Pd(0) species.
• Photocyclization of 4-(dialkylamino)-2-aryl-1-butenes
  作者：Hiromu Aoyama、Junichi Sugiyama、Masamichi Yoshida、Hiroaki Hatori、Akira Hosomi

  DOI：10.1021/jo00037a017

  日期：1992.5

  Irradiation of 4-(dialkylamino)-2-aryl-1-butenes gave cyclization products, 3-methyl-3-arylpyrrolidines, in high yields. These styrylamines formed fluorescent intramolecular exciplexes, but studies based on Stern-Volmer quenching for the fluorescence and the photoreaction suggested that the emissive exciplexes did not participate in the photoreaction.