[Me3SiN=PPh2)2C=GeCl2] | 868528-45-4

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: [Me3SiN=PPh2)2C=GeCl2]
• CAS: 868528-45-4
• 化学式: C₃₁H₃₈Cl₂GeN₂P₂Si₂
• 分子量: 700.271
• InChiKey: ZPYRXYOSZINAMN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  9.0
• 重原子数：
  40.0
• 可旋转键数：
  8.0
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.19
• 拓扑面积：
  24.72
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  [(Me3SiN=PPh2)2C=Ge→Ge=C(PPh2=NSiMe3)2] 、 bis-triphenylphosphine-palladium(II) chloride 以 四氢呋喃 为溶剂， 以47%的产率得到四(三苯基膦)钯
  参考文献：
  名称：

  Synthesis of Novel Metal−Germavinylidene Complexes from Bisgermavinylidene

  摘要：

  The bisgermavinylidene [(Me3SiN=PPh2)(2)C=Ge -> Ge=C(PPh2=NSiMe3)(2)] (1) has been used as the source of unstable germavinylidene for the synthesis of a series of metal-germavinylidene complexes. Treatment of 1 with M(PPh3)(4) (M = Ni, Pd) afforded the metal-germavinylidene complexes [{(Me3SiN=PPh2)(2)C=Ge}(2)Ni(PPh3)2] (2) and [{(Me3SiN=PPh2)(2)C= Ge-mu(2)}Pd(PPh3)](2) (3), respectively. The germavinylidene moiety from 1 acts as a two-electron terminal and bridging ligand, respectively. Similar reaction of I with AgCl or AuI gave [(Me3SiN=PPh2)(2)C=Ge(Ag)(Cl)](2) (5) and [(Me3SiN=PPh2)(2)C=Ge(Au)(I)](2) (6), respectively. The result has shown that the germavinylidene moiety from I behaves as a Lewis base and undergoes an insertion reaction into the metal-halogen bond. X-ray structures of 2, 3, 5, and 6 have been determined.

  DOI：

  10.1021/om0503085