pentaphenoxy(2-pyridylmethylamino)cyclotriphosphazene | 163040-28-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: pentaphenoxy(2-pyridylmethylamino)cyclotriphosphazene
• 英文别名: 2,4,4,6,6-pentaphenoxy-N-(pyridin-2-ylmethyl)-1,3,5-triaza-2λ5,4λ5,6λ5-triphosphacyclohexa-1,3,5-trien-2-amine
• CAS: 163040-28-6
• 化学式: C₃₆H₃₂N₅O₅P₃
• 分子量: 707.602
• InChiKey: SRBXTIIOTSXWFL-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  10.1
• 重原子数：
  49
• 可旋转键数：
  13
• 环数：
  7.0
• sp3杂化的碳原子比例：
  0.03
• 拓扑面积：
  108
• 氢给体数：
  1
• 氢受体数：
  10

反应信息

• 作为反应物：
  描述：

  [PtCl₄(EtCN)2] 、 pentaphenoxy(2-pyridylmethylamino)cyclotriphosphazene 以 氯仿 为溶剂， 以6%的产率得到dichloropentaphenoxy(2-pyridylmethylamino)cyclotriphosphazeneplatinum(II)
  参考文献：
  名称：

  Reactions of platinum nitrile complexes with cyclotriphosphazenes containing pyridylalkylamino groups

  摘要：

  Reactions of platinum(II) and platinum(IV) nitrile complexes with polydentate ligands, such as pentaphenoxy(2-pyridylmethylamino)cyclotriphosphazene, pentaphenoxy(3-pyridylmethylamino)cyclotriphosphazene, and pentaphenoxy(2-pyridylethylamino)cyclotriphosphazene, were studied. Platinum(IV) is reduced to platinum(II) upon complex formation; the pyridine and alkylamine nitrogen atoms coordinate to platinum(II) to form chelate rings. The compounds obtained were characterized by H-1 and P-31 NMR and IR spectroscopy, FAB mass spectrometry, and other methods.

  DOI：

  10.1134/s1070363206040074
• 作为产物：
  描述：

  2-氨甲基吡啶 、 2-chloro-2,4,4,6,6-pentaphenoxycyclotriphosphazene 以 四氢呋喃 为溶剂， 反应 40.0h， 以78%的产率得到pentaphenoxy(2-pyridylmethylamino)cyclotriphosphazene
  参考文献：
  名称：

  具有（2-吡啶基甲基氨基）基团的磷酸酯I.五苯氧基（2-吡啶基甲基氨基）-环三磷腈及其硝酸铜（II），氯化铂（II）和硝酸钴（II）配合物的合成和晶体结构

  摘要：

  （2-吡啶基甲基氨基）取代的环三磷腈N 3 P 3（OC 6 H 5）5（NHCH 2（C 5 H 4 N）-2）（1）与硝酸铜（II），铂（II）的反应氯化物和硝酸钴（II）生成稳定的络合物[Cu（NO 3）2 ·（1）2 ]（1a），[PtCl 2 ·（1）]（1b），[Co（NO 3）2 ·（1）]（1c）。这些金属配合物的X射线晶体学研究揭示了多功能配体的不同配位行为。

  DOI：

  10.1002/cber.19961291227

文献信息

• Synthesis and molecular structure of platinum(II) complexes with cyclotriphosphazenes containing pyridylalkylamino and pyridylmethoxy groups
  作者：S. A. Simanova、T. V. Kuznetsova、V. N. Demidov、E. A. Aleksandrova、U. Diefenbach

  DOI：10.1134/s1070363207110059

  日期：2007.11

  The interaction of platinum(II) nitrile complexes with polydentate ligands, pentaphenoxy(2-pyridylmethylamino) cyclotriphosphazene (L-1), pentaphenoxy( 3-pyridylmethylamino) cyclotriphosphazene (L-2), pentaphenoxy[2-(2- pyridyl) ethylamino] cyclotriphosphazene (L-3), and pentaphenoxy(2-pyridylmethoxy)cyclotriphosphazene (L-4), was studied. The synthesized complexes were characterized by single-crystal X-ray diffraction, H-1 and P-31 NMR spectroscopy, IR spectroscopy, FAB mass spectrometry, and other methods. In complexation of phosphazenes L-1 L-3 with Pt(II) ions, nitrogen atoms of the pyridine ring and alkylamine fragment participate in the coordination to form chelate rings. In the complex with L-4, the substituted phosphazene is coordinated via nitrogen atoms of the pyridyl group and cyclotriphosphazene ring to form a seven-membered ring.
• Diefenbach, Ursula; Kretschmann, Michael; Cavdarci, Oemer, Phosphorus, Sulfur and Silicon and the Related Elements, 1994, vol. 94, # 1-4, p. 415 - 416
  作者：Diefenbach, Ursula、Kretschmann, Michael、Cavdarci, Oemer

  DOI：——

  日期：——