[UO2(bypO2)(H2O)2(SO4)] | 1238847-66-9

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 吡啶及其衍生物
• 英文名称: [UO2(bypO2)(H2O)2(SO4)]
• 英文别名: [UO2(2,2'-bipyridine-N,N'-dioxide)(water)2(sulfate)]
• CAS: 1238847-66-9
• 化学式: C₁₀H₁₂N₂O₁₀SU
• 分子量: 590.308
• InChiKey: QVTAJSOJXFIFLP-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  N,N'-二氧化-2,2'-联吡啶 、 uranyl sulfate trihydrate 以 水 为溶剂， 生成 [UO2(bypO2)(H2O)2(SO4)]
  参考文献：
  名称：

  Structural and spectroscopy studies of complexes of the uranyl ion with 2,2′-bipyridine-N,N′-dioxide

  摘要：

  2,2'-Bipyridine-N,N'-dioxide (bypO(2) = L) complexes of the composition [UO2(bypO(2))(2)(NO3)(2)]center dot 2H(2)O (UO2-L-2-NO3), [UO2(bypO(2))2H(2)O](ClO4)(2) (UO2-L-2-ClO4) and [UO(2)bypO(2)(H2O)(2)SO4] (UO2-L-SO4) have been prepared by the reactions of the respective hydrated uranyl salts with the bypO(2) ligand in water. The structures of the complexes were elucidated using elemental and thermal analyses, IR and luminescence spectroscopy as well as luminescence lifetime measurements. The IR spectra show that the bonding between uranium and bypO(2), as well as uranium and water or a counter ion (NO3- and SO42-) is formed. The nitrate or sulfate groups coordinate to the central metal ions in a monodentate manner. From TG-DTA curves, the nature of the water molecules present in the complexes and the decomposition temperature of the dehydrated uranyl complexes were determined. The thermal stability of the anhydrous uranyl complexes increases in the series: (UO2-L-2-NO3) < (UO2-L-2-ClO4) < (UO2-L-SO4). All the compounds show green-yellow intense luminescence. The main fluorescence bands and the emission lifetimes in these complexes were determined. The luminescence spectra of all the prepared complexes differ from each other with respect to their peak maxima positions. The luminescence lifetimes also vary. The structure of the (UO2-L-SO4) complex was determined by X-ray single-crystal analysis. (C) 2010 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.poly.2010.04.001