Perfluoro-3-[3-[3-(propoxy)propoxy]propoxy]propanoyl fluoride | 122075-99-4

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 酰卤
• 英文名称: Perfluoro-3-[3-[3-(propoxy)propoxy]propoxy]propanoyl fluoride
• 英文别名: 2,2,3,3-tetrafluoro-3-[1,1,2,2,3,3-hexafluoro-3-[1,1,2,2,3,3-hexafluoro-3-(1,1,2,2,3,3,3-heptafluoropropoxy)propoxy]propoxy]propanoyl fluoride
• CAS: 122075-99-4
• 化学式: C₁₂F₂₄O₄
• 分子量: 664.09
• InChiKey: QKZFIPVEGIRMOQ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  8.2
• 重原子数：
  40
• 可旋转键数：
  13
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.92
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  28

反应信息

• 作为反应物：
  描述：

  Perfluoro-3-[3-[3-(propoxy)propoxy]propoxy]propanoyl fluoride 、 六氟环氧丙烷 生成 2,3,3,3-tetrafluoro-2-[1,1,2,2,3,3-hexafluoro-3-[1,1,2,2,3,3-hexafluoro-3-[1,1,2,2,3,3-hexafluoro-3-(1,1,2,2,3,3,3-heptafluoropropoxy)propoxy]propoxy]propoxy]propanoyl fluoride
  参考文献：
  名称：

  OKA, MASAXIKO;KISINEH, OSAMU;SAJTO, XIDEHYA;KUNIENEH, MASUO

  摘要：

  DOI：

文献信息

• CARBOXYLIC ACID ESTER/CARBAMATE COMPOUND WITH POLYMERIZABLE FUNCTIONAL GROUP AND FLUORINE ATOM GROUP, AND MANUFACTURING METHOD THEREFOR
  申请人：UNIMATEC CO., LTD.

  公开号：US20160185714A1

  公开（公告）日：2016-06-30

  Provided are a fluorine-containing monomer soluble in a hydrocarbon-based solvent as well as excellent in water and oil repellence, and a manufacturing method therefor. The fluorine-containing monomer is a carboxylic acid ester/carbamate compound having a polymerizable functional group and a fluorine atom group, and represented by the following general formula: C a F 2a+1 O—(C b F 2b O) c —C 2 F 4 COO—Z—(CONHR) d . The method for manufacturing the carboxylic acid ester/carbamate compound is comprised of the steps of making an isocyanate compound having a polymerizable functional group react with an alcohol such as a polyalkylene glycol, a cycloalkane dimethanol, or a polyhydric alcohol to produce a hydroxycarbamate, and subsequently making the resulting hydroxycarbamate react with a perfluoropolyether carboxylic acid halide.

  提供了一种可溶于烃基溶剂且具有优异的水和油抗性的含氟单体及其制造方法。该含氟单体是一种具有可聚合官能团和氟原子团的羧酸酯/氨基甲酸酯化合物，由以下通式表示：CaF2a+1O—(CbF2bO)c—C2F4COO—Z—(CONHR)d。制造羧酸酯/氨基甲酸酯化合物的方法包括以下步骤：使具有可聚合官能团的异氰酸酯化合物与醇反应，例如聚烷基醚、环烷基二甲醇或多元醇，生成羟基氨甲酸酯，然后使所得的羟基氨甲酸酯与全氟聚醚羧酸卤化物反应。
• Carboxylic acid ester compound having polymerizable functional group and fluorine atom group, and method for producing same
  申请人：UNIMATEC CO., LTD.

  公开号：US10125107B1

  公开（公告）日：2018-11-13

  Provided are a fluorine-containing monomer capable of being dissolved in a general organic solvent such as a hydrocarbon solvent and simultaneously having excellent water and oil repellency, and a method for producing the fluorine-containing monomer. The fluorine-containing monomer is a carboxylic acid ester compound having a polymerizable functional group and a fluorine atom group, represented by the following general formula: CaF2a+1O—(CbF2bO)c—C2F4COOR. The method is a process for producing the carboxylic acid ester compound, characterized by that any one of an isocyanulate derivative, a phthalic acid derivative and a cycloalkane dialcohol modified (meth)acrylate each having a terminal hydroxyl group is made to react with a perfluoropolyether carboxylic acid halide.

  提供了一种含氟单体，能够溶解在一般有机溶剂（如烃类溶剂）中，同时具有优异的防水和防油性能，以及一种制备含氟单体的方法。该含氟单体是一种具有聚合功能基团和氟原子基团的羧酸酯化合物，由下列通式表示：CaF2a+1O—(CbF2bO)c—C2F4COOR。该方法是一种生产羧酸酯化合物的过程，其特征在于，使用具有末端羟基的异氰酸酯衍生物、邻苯二甲酸衍生物和环烷二醇改性（甲）基丙烯酸酯之一，与全氟聚醚羧酸卤化物反应。
• CARBOXYLIC ESTER / CARBAMATE COMPOUND WITH POLYMERIZABLE FUNCTIONAL GROUP AND FLUORINE ATOM GROUP, AND MANUFACTURING METHOD THEREFOR
  申请人：Unimatec Co., Ltd.

  公开号：EP3127897A1

  公开（公告）日：2017-02-08

  Provided are a fluorine-containing monomer soluble in a hydrocarbon-based solvent as well as excellent in water and oil repellence, and a manufacturing method therefor. The fluorine-containing monomer is a carboxylic acid ester/carbamate compound having a polymerizable functional group and a fluorine atom group, and represented by the following general formula: CaF2a+1O-(CbF2bO)c-C2F4COO-Z-(CONHR)d. The method for manufacturing the carboxylic acid ester/carbamate compound is comprised of the steps of making an isocyanate compound having a polymerizable functional group react with an alcohol such as a polyalkylene glycol, a cycloalkane dimethanol, or a polyhydric alcohol to produce a hydroxycarbamate, and subsequently making the resulting hydroxycarbamate react with a perfluoropolyether carboxylic acid halide.

  本发明提供了一种可溶于烃基溶剂、防水防油性能优异的含氟单体及其制造方法。该含氟单体是一种具有可聚合官能团和氟原子基团的羧酸酯/氨基甲酸酯化合物，由以下通式表示：CaF2a+1O-(CbF2bO)c-C2F4COO-Z-(CONHR)d。制造羧酸酯/氨基甲酸酯化合物的方法包括以下步骤：使具有可聚合官能团的异氰酸酯化合物与醇类（如聚烷二醇、环烷二甲醇或多元醇）反应生成羟基氨基甲酸酯，然后使生成的羟基氨基甲酸酯与全氟聚醚羧酸卤化物反应。
• CARBOXYLIC ACID ESTER COMPOUND HAVING POLYMERIZABLE FUNCTIONAL GROUP AND FLUORINE ATOM GROUP, AND METHOD FOR PRODUCING SAME
  申请人：Unimatec Co., Ltd.

  公开号：EP3395794A1

  公开（公告）日：2018-10-31

  Provided are a fluorine-containing monomer having excellent water repellency and oil repellency that can be dissolved in common organic solvents such as hydrocarbon solvents, and a method for producing the same. A carboxylic acid ester compound having a polymerizable functional group and a fluorine atom group represented by the following general formula. CaF2a+1O-(CbF2bO)c-C2F4COOR Also, a method for producing the carboxylic acid ester compound characterized by reacting any one of an isocyanurate derivative having an end hydroxyl group, a phthalic acid derivative, and a cycloalkane dialcohol-modified (meth)acrylate, with a perfluoropolyether carboxylic acid halide.

  本发明提供了一种具有优异憎水性和憎油性、可溶解于普通有机溶剂（如烃类溶剂）的含氟单体，以及生产该单体的方法。一种羧酸酯化合物，其可聚合官能团和氟原子基团由以下通式表示。CaF2a+1O-(CbF2bO)c-C2F4COOR 还有，生产该羧酸酯化合物的方法，其特征在于使具有端羟基的异氰尿酸酯衍生物、邻苯二甲酸衍生物和环烷二醇改性(甲基)丙烯酸酯中的任一种与全氟聚醚羧酸卤化物反应。
• US9604918B2
  申请人：——

  公开号：US9604918B2

  公开（公告）日：2017-03-28