bis(2-amino-1-cyclopentene-1-dithiocarboxylato)oxovanadium(IV) | 80290-83-1

• 分子结构分类: 有机化合物 - 有机硫化合物 - 硫代羰基化合物
• 英文名称: bis(2-amino-1-cyclopentene-1-dithiocarboxylato)oxovanadium(IV)
• CAS: 80290-83-1
• 化学式: C₁₂H₁₆N₂OS₄V
• 分子量: 383.477
• InChiKey: VOZWCEZYZVNAIY-UHFFFAOYSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  硫酸氧钒水合物 、 2-氨基-1-环戊烯-1-二硫代甲酸 以 sodium hydroxide 、 乙醇 、 水 为溶剂， 以87%的产率得到bis(2-amino-1-cyclopentene-1-dithiocarboxylato)oxovanadium(IV)
  参考文献：
  名称：

  Magnetic properties and coordination environments of oxovanadium(IV) within VO(IV)N2S2 and VO(IV)S4 chromophores

  摘要：

  Oxovanadium(IV) complexes of the 2-amino-1-cyclopentene-1-dithiocarboxylate (acdc) and 2-methylamino-1-cyclopentene-1-dithiocarboxylate (N-CH(3)acdc) anion have been synthesized and characterized by using IR, EPR, magnetic susceptibility and XPS measurements to elucidate the coordination environment of oxovanadium(IV) complexes of the acdc ligand and its derivative. The corresponding spin-Hamiltonian parameters, [g] values and hyperfine coupling constants, (A) have been examined for the prepared complexes having VO(IV)N2S2 and VO(IV)S-4 chromophore. The EPR data confirm its usefulness in the characterization of the coordination environments of these compounds. The XPS studies have also provided us with valuable information on the binding properties of VO(acdc)(2) and VO(N-CH(3)acdc)(2). The magnetic susceptibility, coupled with the V=O stretching frequency suggest the presence of some degree of magnetic interaction in these compounds. (C) 2000 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s0277-5387(00)00528-3

文献信息

• Dey, K.; Maiti, R. K.; Bhar, J. K., Indian Journal of Chemistry, Section A: Inorganic, Physical, Theoretical and Analytical, 1981, vol. 20, # 8, p. 810 - 813
  作者：Dey, K.、Maiti, R. K.、Bhar, J. K.

  DOI：——

  日期：——