[Cu(2,2'-(2-methyl-2-(pyridin-2-yl)propane-1,3-diyl)bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)diphenol(2-))(MeOH)] | 1148128-89-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 二嗪类
• 英文名称: [Cu(2,2'-(2-methyl-2-(pyridin-2-yl)propane-1,3-diyl)bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)diphenol(2-))(MeOH)]
• CAS: 1148128-89-5
• 化学式: C₂₄H₂₅CuN₃O₃
• 分子量: 467.027
• InChiKey: HBXIWGKHLIHSHK-FNYVYRHBSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  甲醇 、 copper(II) choride dihydrate 、 2,2'-(2-methyl-2-(pyridin-2-yl)propane-1,3-diyl)bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)diphenol 在 triethylamine 作用下， 以 甲醇 为溶剂， 以70%的产率得到[Cu(2,2'-(2-methyl-2-(pyridin-2-yl)propane-1,3-diyl)bis(azan-1-yl-1-ylidene)bis(methan-1-yl-1-ylidene)diphenol(2-))(MeOH)]
  参考文献：
  名称：

  Synthesis and Characterization of Polynuclear Copper(II) Complexes with Pyridylbis(phenol) Ligands

  摘要：

  Three new pyridylbis(phenol) ligands with imine (H2Limine), amine (H2Lamine), or amide (H4L amide) linkages, along with their copper complexes, were synthesized and characterized. Treatment of H2Limine with copper(II) in the presence of base produced mononuclear copper complex [Cu(L-imine)(MeOH)] (1), while the same procedure with H2Lamine produced trinuclear [Cu-3(L-amine)(2)(CH3CN)(2)](ClO4)(2) (2). The more rigid H4Lamide forms tetranuclear [Cu-4(L-amide)(2)(H2O)(4)] (3), which upon recrystallization yielded crystals of hexanuclear [Cu-6(HLamide)(4)(H2O)(2)] (4).

  DOI：

  10.1021/ic9000768