5,11,17,23-tetra-tert-butyl-25,26,27-tris<(ethoxycarbonyl)methoxy>-28-<(N,N-diethylcarbamoyl)methoxy>calix<4>arene | 143722-39-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 5,11,17,23-tetra-tert-butyl-25,26,27-tris<(ethoxycarbonyl)methoxy>-28-<(N,N-diethylcarbamoyl)methoxy>calix<4>arene
• 英文别名: 5,11,17,23-tetra-tert-butyl-25,26,27-tris(ethoxycarbonylmethoxy)-28-diethylcarbamoylmethoxycalix<4>arene；Ethyl 2-[[5,11,17,23-tetratert-butyl-26-[2-(diethylamino)-2-oxoethoxy]-27,28-bis(2-ethoxy-2-oxoethoxy)-25-pentacyclo[19.3.1.13,7.19,13.115,19]octacosa-1(24),3,5,7(28),9,11,13(27),15(26),16,18,21(25),22-dodecaenyl]oxy]acetate
• CAS: 143722-39-8；144371-58-4
• 化学式: C₆₂H₈₅NO₁₁
• 分子量: 1020.36
• InChiKey: BDDPGBBEOSHMDM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  15.4
• 重原子数：
  74
• 可旋转键数：
  24
• 环数：
  5.0
• sp3杂化的碳原子比例：
  0.55
• 拓扑面积：
  136
• 氢给体数：
  0
• 氢受体数：
  11

反应信息

• 作为产物：
  描述：

  5,11,17,23-tetra-tert-butyl-25,26,27-tris(ethoxycarbonylmethoxy)-28-carboxymethoxycalix[4]arene 在 氯化亚砜 、 三乙胺 作用下， 以 苯 为溶剂， 反应 6.0h， 生成 5,11,17,23-tetra-tert-butyl-25,26,27-tris<(ethoxycarbonyl)methoxy>-28-<(N,N-diethylcarbamoyl)methoxy>calix<4>arene
  参考文献：
  名称：

  Unsymmetrical calix[4]arene ionophore/silicone rubber composite membranes for high-performance sodium ion-sensitive field-effect transistors

  摘要：

  As neutral carriers for sodium ion-sensitive field-effect transistors (ISFETs), unsymmetrical calix[4]arene ionophores have been designed which possess three ester linkages and an amide linkage as the cation-binding sites. One of the calix[4]arene derivatives are highly soluble In silicone rubber, which is very adhesive to inorganic FET gates, thus affording stable sensing membranes for the ISFET. The resulting sodium ISFETs based on the calixarene ionophore/silicone rubber composite showed high sodium ion selectivity and high sensor durability.

  DOI：

  10.1021/ac00045a009

文献信息

• Arnaud-Neu, Francoise; Barrett, Geraldine; Cremin, Suzanne, Journal of the Chemical Society. Perkin transactions II, 1992, # 7, p. 1119 - 1125
  作者：Arnaud-Neu, Francoise、Barrett, Geraldine、Cremin, Suzanne、Deasy, Mary、Ferguson, George、et al.

  DOI：——

  日期：——
• Arnaud-Neu Francoise, Barrett Geraldine, Cremin Suzanne, Deasy Mary, Ferg+, J. Chem. Soc. Perkin Trans. 2, (1992) N 7, S 1119-1125
  作者：Arnaud-Neu Francoise, Barrett Geraldine, Cremin Suzanne, Deasy Mary, Ferg+

  DOI：——

  日期：——