2-hydroxy-5-(11-tetrahydropyranyloxyundecyloxy)benzaldehyde | 201673-27-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 酚类
• 英文名称: 2-hydroxy-5-(11-tetrahydropyranyloxyundecyloxy)benzaldehyde
• 英文别名: 5-(11-tetrahydropyranyloxyundecyloxy)salicylaldehyde；2-Hydroxy-5-[11-(oxan-2-yloxy)undecoxy]benzaldehyde
• CAS: 201673-27-0
• 化学式: C₂₃H₃₆O₅
• 分子量: 392.536
• InChiKey: SQFIWEVPIGFPAD-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.4
• 重原子数：
  28
• 可旋转键数：
  15
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  65
• 氢给体数：
  1
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  phenylmalonic aldehyde 、 乙二胺 、 2-hydroxy-5-(11-tetrahydropyranyloxyundecyloxy)benzaldehyde 以 二氯甲烷 为溶剂， 反应 18.0h， 以34%的产率得到8-(3-(11-tetrahydropyranyloxyundecyloxy)-6-hydroxyphenyl)-2-phenyl-4,7-diazocta-2,7-dien-1-al
  参考文献：
  名称：

  Side chain liquid crystal polyacrylate and polymethacrylate nickel complexes free from covalent cross-linking

  摘要：

  Non-symmetrical nickel(H) complexes containing a single acrylate or methacrylate motif have been synthesised and polymerised radically in tetrohydrofuran solation using AIBN as the initiator. This results in the incorporation of the metal complexes into a polyacrylate and a polymethacrylate as freely mobile side chains, free from cross-linking. Whilst the monomers are non-liquid crystalline, the polymers show smectic A liquid crystal phases.

  DOI：

  10.1080/15421400490436412
• 作为产物：
  描述：

  11-溴-1-十一醇 在 氢氧化钾 、 三正丁胺 、 四氯化锡 、 对甲苯磺酸 作用下， 以 乙醇 、 二氯甲烷 、 甲苯 为溶剂， 反应 24.0h， 生成 2-hydroxy-5-(11-tetrahydropyranyloxyundecyloxy)benzaldehyde
  参考文献：
  名称：

  Side chain liquid crystal polyacrylate and polymethacrylate nickel complexes free from covalent cross-linking

  摘要：

  Non-symmetrical nickel(H) complexes containing a single acrylate or methacrylate motif have been synthesised and polymerised radically in tetrohydrofuran solation using AIBN as the initiator. This results in the incorporation of the metal complexes into a polyacrylate and a polymethacrylate as freely mobile side chains, free from cross-linking. Whilst the monomers are non-liquid crystalline, the polymers show smectic A liquid crystal phases.

  DOI：

  10.1080/15421400490436412

文献信息

• METAL-CONTAINING SIDE CHAIN LIQUID CRYSTAL POLYMERS
  申请人：THE SECRETARY OF STATE FOR DEFENCE

  公开号：EP0927155A1

  公开（公告）日：1999-07-07
• US6184322B1
  申请人：——

  公开号：US6184322B1

  公开（公告）日：2001-02-06
• [EN] METAL-CONTAINING SIDE CHAIN LIQUID CRYSTAL POLYMERS<br/>[FR] POLYMERES DE CRISTAL LIQUIDE A CHAINE LATERALE CONTENANT DU METAL
  申请人：THE SECRETARY OF STATE FOR DEFENCE

  公开号：WO1997049671A1

  公开（公告）日：1997-12-31

  (EN) A group of liquid crystalline compounds defined by Formulas (1) and (2) including polymers, monomers, oligomers and intermediates for their preparation. Also included are symmetric and non-symmetric poly(dimethylsiloxy) compounds having end groups derived from Formulas (1) and (2).(FR) Groupe de composés cristallins liquides définis par les formules (1) et (2), comprenant des polymères, des monomères, des oligomères et des intermédiaires pour les préparer. L'invention porte également sur des composés poly(diméthylsiloxy) symétriques et non symétriques possédant des groupes terminaux dérivés des formules (1) et (2).
• Side chain liquid crystal polyacrylate and polymethacrylate nickel complexes free from covalent cross-linking
  作者：Peter Styring、Isabel Saez

  DOI：10.1080/15421400490436412

  日期：2004.1

  Non-symmetrical nickel(H) complexes containing a single acrylate or methacrylate motif have been synthesised and polymerised radically in tetrohydrofuran solation using AIBN as the initiator. This results in the incorporation of the metal complexes into a polyacrylate and a polymethacrylate as freely mobile side chains, free from cross-linking. Whilst the monomers are non-liquid crystalline, the polymers show smectic A liquid crystal phases.