4-(4-ethoxyphenyl)-5,5-difluoro-1-(4-fluoro-3-phenoxyphenyl)-4-methyl-2-pentene | 104918-42-5

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 4-(4-ethoxyphenyl)-5,5-difluoro-1-(4-fluoro-3-phenoxyphenyl)-4-methyl-2-pentene
• 英文别名: 4-[4-(4-ethoxyphenyl)-5,5-difluoro-4-methylpent-2-enyl]-1-fluoro-2-phenoxybenzene
• CAS: 104918-42-5
• 化学式: C₂₆H₂₅F₃O₂
• 分子量: 426.479
• InChiKey: VBDDRWUBYCYFIN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  7.9
• 重原子数：
  31
• 可旋转键数：
  9
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.23
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  5

反应信息

• 作为反应物：
  描述：

  4-(4-ethoxyphenyl)-5,5-difluoro-1-(4-fluoro-3-phenoxyphenyl)-4-methyl-2-pentene 在 aluminum nickel 氢气 作用下， 以 乙醇 、 正己烷 、 甲苯 为溶剂， 生成 2-(4-ethoxyphenyl)-1,1-difluoro-5-(4-fluoro-3-phenoxyphenyl)-2-methylpentane
  参考文献：
  名称：

  US4743622

  摘要：

  公开号：

文献信息

• Certain diaryl-pentane derivatives having pesticidal properties
  申请人：Schering Aktiengesellschaft

  公开号：US04743622A1

  公开（公告）日：1988-05-10

  The invention relates to new aromatic alkane derivatives of the general formula ##STR1## in which R.sub.1 is aryl or aryl substituted by C.sub.1-4 alkyl, halo-C.sub.1-4 alkyl, phenyl-C.sub.1-4 alkyl, C.sub.2-4 alkenyl, halo-C.sub.2-4 alkenyl, phenyl-C.sub.2-4 alkenyl, C.sub.2-4 alkynyl, halo-C.sub.2-4 alkynyl, phenyl-C.sub.2-4 alkynyl, C.sub.1-4 alkoxy, halo-C.sub.1-4 alkoxy, phenyl-C.sub.1-4 alkoxy, C.sub.2-4 alkenyloxy, halo-C.sub.2-4 alkenyloxy, phenyl-C.sub.2-4 alkenyloxy, C.sub.2-4 alkynyloxy, halo-C.sub.2-4 alkynyloxy, phenyl-C.sub.2-4 alkynyloxy, alkylsulphonyloxy, haloalkylsulphonyloxy, arylsulphonyloxy, halo, cyano, nitro, aryloxy, haloaryloxy, C.sub.1-4 alkyl-aryloxy, or nitroaryloxy, R.sub.2 is hydrogen or C.sub.1-4 alkyl, R.sub.3 is hydrogen, cyano or ethynyl, R.sub.4 is phenyl or pyridyl or these groups substituted by one or more of C.sub.1-6 alkyl, halo-C.sub.1-6 alkyl, phenyl-C.sub.1-6 alkyl, C.sub.1-6 alkyl interrupted by an O-, N- or S- atom, C.sub.2-4 alkenyl, halo-C.sub.2-4 alkenyl, phenyl-C.sub.2-4 alkenyl, C.sub.1-4 alkoxy, halo-C.sub.1-4 alkoxy, phenyl-C.sub.1-4 alkoxy, C.sub.2-4 alkenyloxy, halo-C.sub.2-4 alkenyloxy, phenyl-C.sub.2-4 alkenyloxy, C.sub.2-4 alkynyloxy, halo-C.sub.2-4 alkynyloxy, phenyl-C.sub.2-4 alkynyloxy, aryloxy, haloaryloxy, C.sub.1-4 alkylaryloxy, arylamino, haloarylamino, C.sub.1-4 alkylarylamino, aryl-N-C.sub.1-4 alkylamino, aryl-N-C.sub.1-4 acylamino, aroyl, haloaroyl, C.sub.1-4 alkylaroyl, aryl, haloaryl, C.sub.1-4 alkylaryl or halo, and pesticidal compositions containing these compounds as well as processes for their preparation.

  本发明涉及一种新的芳香族烷基衍生物，其通式为##STR1##其中，R.sub.1是芳基或被C.sub.1-4烷基、卤代C.sub.1-4烷基、苯基-C.sub.1-4烷基、C.sub.2-4烯基、卤代C.sub.2-4烯基、苯基-C.sub.2-4烯基、C.sub.2-4炔基、卤代C.sub.2-4炔基、苯基-C.sub.2-4炔基、C.sub.1-4烷氧基、卤代C.sub.1-4烷氧基、苯基-C.sub.1-4烷氧基、C.sub.2-4烯氧基、卤代C.sub.2-4烯氧基、苯基-C.sub.2-4烯氧基、C.sub.2-4炔氧基、卤代C.sub.2-4炔氧基、苯基-C.sub.2-4炔氧基、烷基磺酰氧基、卤代烷基磺酰氧基、芳基磺酰氧基、卤素、氰基、硝基、芳氧基、卤代芳氧基、C.sub.1-4烷基芳氧基或硝基芳氧基，R.sub.2是氢或C.sub.1-4烷基，R.sub.3是氢、氰基或乙炔基，R.sub.4是苯基或吡啶基，或这些基团中的一个或多个被C.sub.1-6烷基、卤代C.sub.1-6烷基、苯基-C.sub.1-6烷基、被O-、N-或S-原子中断的C.sub.1-6烷基、C.sub.2-4烯基、卤代C.sub.2-4烯基、苯基-C.sub.2-4烯基、C.sub.1-4烷氧基、卤代C.sub.1-4烷氧基、苯基-C.sub.1-4烷氧基、C.sub.2-4烯氧基、卤代C.sub.2-4烯氧基、苯基-C.sub.2-4烯氧基、C.sub.2-4炔氧基、卤代C.sub.2-4炔氧基、苯基-C.sub.2-4炔氧基、芳氧基、卤代芳氧基、C.sub.1-4烷基芳氧基、芳基氨基、卤代芳基氨基、C.sub.1-4烷基芳基氨基、芳基-N-C.sub.1-4烷基氨基、芳基-N-C.sub.1-4酰基氨基、芳基酰基、卤代芳基酰基、C.sub.1-4烷基芳基酰基、芳基、卤代芳基、C.sub.1-4烷基芳基或卤素，以及含有这些化合物的杀虫剂组合物以及其制备方法。