Ru(2,6-dipicolinic acid)(ethylenediamine)Cl | 149961-87-5

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 杂芳族化合物
• 英文名称: Ru(2,6-dipicolinic acid)(ethylenediamine)Cl
• CAS: 149961-87-5
• 化学式: C₉H₁₁ClN₃O₄Ru
• 分子量: 361.727
• InChiKey: DIGPVKXVMFDGIK-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
  None
• 氢给体数：
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• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  吡啶-2,6-二甲酸 、 水合三氯化钌 、 乙二胺 以 乙醇 、 水 为溶剂， 生成 Ru(2,6-dipicolinic acid)(ethylenediamine)Cl
  参考文献：
  名称：

  Oxidation of organic substrates catalysed by mixed ligand RuIII complexes. Investigation of active catalytic species and termination pathway

  摘要：

  The mixed ligand complexes of the type, [Ru(III)(DPA)(L)Cl] (where DPA=2,6-dipicolinic acid, and L=ethylenediamine, 2,2'-bipyridine or 1,10-phenanthroline) have been synthesised and characterised by spectral, magnetic and cyclic voltammetric studies. The complexes have been used as catalysts for the oxidation of hydrocarbons using iodosylbenzene and tert-butyl hydroperoxide as the oxidants. The formation of intermediate has been investigated in case of the oxidation reaction involving various oxidants and [Ru(III)(DPA)(2,2'-bipy) Cl] as a catalyst. It is observed that the same active intermediate, [Ru(V)(DPA)(2,2'-bipy)(O)], is formed for all of the oxidants. This intermediate catalytically transfers oxygen to the olefin and causes its oxidation. Termination of the catalytic activity is due to the formation of the mu-oxo dimer of the complex, which has been isolated and characterised by elemental analysis, spectral and cyclic voltammetric studies.

  DOI：

  10.1016/0304-5102(93)87104-g