1,1'-bis(β-ferrocenylacryloyl)ferrocene | 12103-20-7

• 英文名称: 1,1'-bis(β-ferrocenylacryloyl)ferrocene
• CAS: 12103-20-7；1073539-16-8；1022224-51-6
• 化学式: C₃₆H₃₀Fe₃O₂
• 分子量: 662.174
• InChiKey: ADOGKYULVNTHGB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
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• 重原子数：
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• 可旋转键数：
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• 环数：
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• sp3杂化的碳原子比例：
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• 拓扑面积：
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• 氢给体数：
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• 氢受体数：
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反应信息

• 作为产物：
  描述：

  二茂铁甲醛 、 1,1'-diacetylferrocene 在 sodium hydroxide 作用下， 以 乙醇 、 水 为溶剂， 以75%的产率得到1,5-dioxo-3-ferrocenyl[5]ferrocenophane
  参考文献：
  名称：

  Microwave-assisted synthesis of 1,5-dioxo-3-substituted [5]ferrocenophanes

  摘要：

  The Claisen-Schmidt reaction between 1,1'-diacetylferrocene and ferrocenecarboxaldehyde under microwave irradiation has been investigated in different conditions. The selective synthesis of 1,5-dioxo-3- ferrocenyl[5]ferrocenophane has been achieved and a simple protocol for its purification was established. The reaction was generally applicable to other non-enolizable aldehydes and the corresponding 1,5-dioxo-3- substituted [5]ferrocenophanes were obtained in high yield within 30 min. (c) 2008 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2008.01.038