2,7-dibromo-9,9-di(1-(2-(2-methoxyethoxy)ethoxy)ethyl)fluorene | 1143579-33-2

• 分子结构分类: 有机化合物 - 苯类化合物 - 苯和取代衍生物
• 英文名称: 2,7-dibromo-9,9-di(1-(2-(2-methoxyethoxy)ethoxy)ethyl)fluorene
• 英文别名: 2,7-dibromo-9,9-bis(2-(2-(2-methoxyethoxy)ethoxy)ethoxy)-9H-fluorene；2,7-Dibromo-9,9-bis[2-[2-(2-methoxyethoxy)ethoxy]ethoxy]fluorene
• CAS: 1143579-33-2
• 化学式: C₂₇H₃₆Br₂O₈
• 分子量: 648.386
• InChiKey: VGSFYLUMLDZGIK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.2
• 重原子数：
  37
• 可旋转键数：
  20
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.56
• 拓扑面积：
  73.8
• 氢给体数：
  0
• 氢受体数：
  8

反应信息

• 作为反应物：
  描述：

  异丙醇频哪醇硼酸酯 、 2,7-dibromo-9,9-di(1-(2-(2-methoxyethoxy)ethoxy)ethyl)fluorene 在 正丁基锂 作用下， 以 四氢呋喃 为溶剂， 反应 0.5h， 生成 2,7-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9,9-di(1-(2-(2-methoxyethoxy)ethoxy)ethyl)fluorene
  参考文献：
  名称：

  Varying Anionic Functional Group Density in Sulfonate-Functionalized Polyfluorenes by a One-Phase Suzuki Polycondensation

  摘要：

  A series of anionically functionalized polyfluorene-based conjugated polyelectrolytes were synthesized by the Suzuki polycondensation of the boronic ester 2,7-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9,9-di(1-(2-(2-methoxyethoxy)ethoxy)ethyl)fluorene with the ionic and nonionic dihalides 2,7-dibromo-9,9-di(6-sodium sulfonate-hexyl) fluorene and 2,7-dibromo-9,9-di( 1(2-(2-methoxyethoxy)ethoxy)ethyl)fluorene. The latter monomer served as a diluent to control the ionic functional group density. The use of the triethylene glycol monomethyl ether derivatives made possible a one-phase polyconclensation in a THF/methanol/Na2CO3(aq) mixture using Pd(PPh3)(4). The one-phase nature of the polymerization was essential to balancing the reactivity of the dihalides so that they were both incorporated into the same polymer and so that the polymer composition became dictated by the monomer feedstock composition: In closely related two-phase reactions, a mixture of polymers, one ionic and one nonionic, was isolated with no control over ionic functional group density possible. Using the one-phase approach, polyfluorene-based polyelectrolytes were synthesized with 2-20 aromatic rings per sulfonate group.

  DOI：

  10.1021/ma4004693
• 作为产物：
  描述：

  2,7-二溴芴 、 1-(2-(2-methoxyethoxy)ethoxy)ethyl bromide 在 lithium diisopropyl amide 作用下， 以 四氢呋喃 为溶剂， 反应 0.5h， 生成 2,7-dibromo-9,9-di(1-(2-(2-methoxyethoxy)ethoxy)ethyl)fluorene
  参考文献：
  名称：

  Varying Anionic Functional Group Density in Sulfonate-Functionalized Polyfluorenes by a One-Phase Suzuki Polycondensation

  摘要：

  A series of anionically functionalized polyfluorene-based conjugated polyelectrolytes were synthesized by the Suzuki polycondensation of the boronic ester 2,7-bis(4,4,5,5-tetramethyl-1,3,2-dioxaborolan-2-yl)-9,9-di(1-(2-(2-methoxyethoxy)ethoxy)ethyl)fluorene with the ionic and nonionic dihalides 2,7-dibromo-9,9-di(6-sodium sulfonate-hexyl) fluorene and 2,7-dibromo-9,9-di( 1(2-(2-methoxyethoxy)ethoxy)ethyl)fluorene. The latter monomer served as a diluent to control the ionic functional group density. The use of the triethylene glycol monomethyl ether derivatives made possible a one-phase polyconclensation in a THF/methanol/Na2CO3(aq) mixture using Pd(PPh3)(4). The one-phase nature of the polymerization was essential to balancing the reactivity of the dihalides so that they were both incorporated into the same polymer and so that the polymer composition became dictated by the monomer feedstock composition: In closely related two-phase reactions, a mixture of polymers, one ionic and one nonionic, was isolated with no control over ionic functional group density possible. Using the one-phase approach, polyfluorene-based polyelectrolytes were synthesized with 2-20 aromatic rings per sulfonate group.

  DOI：

  10.1021/ma4004693

文献信息

• Tuning the structures of polypyridinium salts as bifunctional cathode interfacial layers for all-solution-processed red quantum-dot light-emitting diodes
  作者：Shuguang Fu、Xiaojun Yin、Yang Tang、Guohua Xie、Chuluo Yang

  DOI：10.1016/j.cclet.2022.04.009

  日期：2023.4