nickel N,N'-disalicylidene-3,4-diaminotoluene complex | 14875-71-9

• 分子结构分类: 有机化合物 - 苯类化合物
• 英文名称: nickel N,N'-disalicylidene-3,4-diaminotoluene complex
• 英文别名: Ni(dst)
• CAS: 14875-71-9
• 化学式: C₂₁H₁₆N₂NiO₂
• 分子量: 387.06
• InChiKey: NPAAWUJAPHBYJK-GIXCQGAQSA-L

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
  None
• 可旋转键数：
  None
• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为反应物：
  描述：

  nickel N,N'-disalicylidene-3,4-diaminotoluene complex 以 solid 为溶剂， 生成 nickel(II) oxide
  参考文献：
  名称：

  Spectral studies of complexes of nickel(II) with tetradentate schiff bases having N2O2 donor groups

  摘要：

  Complexes of nickel(II) of N,N'-disalicylidene-1,2-phenylenediamine (H(2)dsp), N,N'-disalicylidene-3,4-diaminotoluene (H(2)dst), 4-nitro-N,N'-disalicylidene-1,2-phenylenediamine (H(2)ndsp) and N,N'-disalicylidene ethylenediamine (H(2)salen) have been prepared and characterised by elemental analysis, electronic, IR, magnetic susceptibility measurement, H-1 NMR and thermal studies. TG studies show that the Ni(dsp) and Ni(salen) complex decomposed in one step and Ni(dst) and Ni(ndsp) complex in two steps. Kinetic and thermodynamic parameters were computed from the thermal decomposition data. The activation energy of either one step decomposition or two step decomposition of complexes lies 72 -95 kJ mol(-1) range. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1386-1425(02)00142-7
• 作为产物：
  描述：

  N,N'-disalicylidene-3,4-diaminotoluene 、 nickel(II) acetate tetrahydrate 以 乙醇 为溶剂， 生成 nickel N,N'-disalicylidene-3,4-diaminotoluene complex
  参考文献：
  名称：

  Spectral studies of complexes of nickel(II) with tetradentate schiff bases having N2O2 donor groups

  摘要：

  Complexes of nickel(II) of N,N'-disalicylidene-1,2-phenylenediamine (H(2)dsp), N,N'-disalicylidene-3,4-diaminotoluene (H(2)dst), 4-nitro-N,N'-disalicylidene-1,2-phenylenediamine (H(2)ndsp) and N,N'-disalicylidene ethylenediamine (H(2)salen) have been prepared and characterised by elemental analysis, electronic, IR, magnetic susceptibility measurement, H-1 NMR and thermal studies. TG studies show that the Ni(dsp) and Ni(salen) complex decomposed in one step and Ni(dst) and Ni(ndsp) complex in two steps. Kinetic and thermodynamic parameters were computed from the thermal decomposition data. The activation energy of either one step decomposition or two step decomposition of complexes lies 72 -95 kJ mol(-1) range. (C) 2002 Elsevier Science B.V. All rights reserved.

  DOI：

  10.1016/s1386-1425(02)00142-7

文献信息

• Transition metal Schiff-base complexes as ligands in tin chemistry. Part 2. A tin-119 Mössbauer spectroscopic investigation of the adducts SnBuⁿ_xCl_3–x(OR)·ML (x= 0 or 1; R = H or alkyl; M = Cu^IIor Ni^II; L = quadridentate Schiff-base ligand)
  作者：Desmond Cunningham、John McGinley

  DOI：10.1039/dt9920001387

  日期：——

  The compound SnCl3(OEt)·EtOH reacts with the complexes ML [M = CuII or NiII; H2L =N,N′-ethylene-bis(salicylideneimine), N,N′-o-phenylenebis(salicylideneimine), or derivatives of these] to give the adducts SnCl3(OEt)·ML. Hydrolysis of the ethoxo adducts in chloroform under ambient conditions yields the adducts SnCl3(OH)·ML. Chloroform solutions of the adducts SnCl4·ML gives similar hydroxo adducts under

  化合物SnCl 3（OEt）·EtOH与配合物ML [M = Cu II或Ni II ; ħ 2 L = Ñ，Ñ ' -亚乙基-双（salicylideneimine），Ñ，Ñ ' - Ö -phenylenebis（salicylideneimine），或这些]衍生物，得到的加合物的SnCl 3（OET）·ML。在环境条件下，乙氧基加合物在氯仿中的水解产生加合物SnCl 3（OH）·ML。加合物SnCl 4 ·ML的氯仿溶液在环境条件下，当M = Cu II时会产生类似的羟基加合物，但当M = Ni II时不会。复合SnBun Cl 2（OH）·H 2 O与ML在–10°C下反应，生成1：1的加合物，但在较高温度下会形成SnBu n Cl（OH） 2 ·H 2 O和SnBu n Cl 3 ·ML。化合物SnBu n Cl 2（OMe）·MeOH与ML在氯仿中反应，生成加合物SnBu n Cl