Forging C−S(Se) Bonds by Nickel‐catalyzed Decarbonylation of Carboxylic Acid and Cleavage of Aryl Dichalcogenides
作者:Jing‐Ya Zhou、Yong‐Ming Zhu
DOI:10.1002/ejoc.202100115
日期:2021.5.7
A practical protocol is developed for the one‐pot construction of C−S(Se) bonds through nickel‐catalyzed decarbonylation of carboxylic acid and aryl dichalcogenides. This approach featured broad substrate scope and good functional group tolerance.
Ni-catalyzed C–S bond cleavage of aryl 2-pyridyl thioethers coupling with alkyl and aryl thiols
作者:Cheng-Yi Wang、Rui Tian、Yong-Ming Zhu
DOI:10.1016/j.tet.2021.132453
日期:2021.10
A nickel-catalyzed C–SPy bond activation reactions to produce a variety of thioethers has been developed. The reaction is promoted by a user-friendly, inexpensive, air and moisture-stable Ni precatalyst. Various aryl 2-pyridyl thioethers and a wide range of alkyl and aryl thiols substrates were tolerated in this process which afforded products in moderate to excellent yields.
The reaction of 1- and 2-naphthols 1 and 2 with a variety of thiols 3 in the presence of trifluoromethanesulfonic acid afforded naphthyl alkyl and aryl sulfides 4 and 5, respectively, in good yields. Similarly naphthyl bis(alkyl) or bis(aryl) sulfides 10-13 were prepared from the corresponding dihydroynaphthalenes 6-9.
An Efficient, Mild and Intermolecular Ullmann-Type Synthesis of Thioethers Catalyzed by a Diol-Copper(I) Complex
作者:Govindasamy Sekar、D. Prasad
DOI:10.1055/s-0029-1217056
日期:2010.1
diaryl sulfides and aryl alkyl sulfides are synthesized under mild reaction conditions from the corresponding aryl iodides and aromatic/aliphatic thiols through Ullmann-type intermolecular coupling reactions in the presence of catalytic amount of easily available novel trans-9,10-dihydro-9,10-ethanoanthracene-11,12-dimethanol-copper(I) bromide complex at 82 ˚C. The catalytic system is not only capable
A nickel-catalyzed decarbonylation or decarbonylation accompanied by decarboxylation cross-coupling reaction of aryl anhydrides with thiophenols as coupling partners was disclosed. This method is promoted by a commercially available, moisture-stable, and inexpensive nickel(II) precatalyst. The process can tolerate a variety of functional groups using ubiquitous aryl anhydrides as cross-coupling precursors